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The longest wavelength of He^(+) when it...

The longest wavelength of `He^(+)` when its electron return to third Bohr orbit is ‘m' then shortest wavelength of `Be^(3+)` in the corresponding transition series in terms of 'm' is

A

`(7)/(64)`m

B

`(5)/(36)m`

C

`(64)/(7)m`

D

`(53)/(8)`m

Text Solution

Verified by Experts

The correct Answer is:
A

`(1)/(lambda_(He))=RZ^(2)[(1)/(n_(1)^(2))-(1)/(n_(2)^(2))]`
`(1)/(m)= R xx4[(1)/(9) -(1)/(16)]=(7R)/(36)" " …(i)`
`(1)/(lambda_(Be^(3+)))= R xx 16 [ (1)/(9) -(1)/(oo)]=(16R)/(9)" "…(ii)`
Dividing eq. (i) by (ii)
`(lambda_(Be^(3+)))/(m)=(7xx9)/(16xx36), lambda_(Be^(3+))=(7)/(64)m`
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