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Debye-Huckel Onsager equation for strong...

Debye-Huckel Onsager equation for strong electrolytes:
`wedge=wedge_(o)-Asqrt(c)`
Which of the following equality holds?

A

`wedge=wedge_(o)` as `C to sqrt(A)`

B

`wedge=wedge_(o)` as `Cto oo`

C

`wedge=wedge_(o)` as `C to 0`

D

`wedge=wedge_(o)` as `C to 1`

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The correct Answer is:
To solve the problem regarding the Debye-Huckel Onsager equation for strong electrolytes, we need to analyze the given equation: \[ \lambda = \lambda_0 - A\sqrt{c} \] where: - \(\lambda\) is the molar conductivity, - \(\lambda_0\) is the molar conductivity at infinite dilution, - \(A\) is a constant, - \(c\) is the concentration of the electrolyte. ### Step-by-Step Solution: 1. **Understanding the Equation**: The equation describes how the molar conductivity (\(\lambda\)) of a strong electrolyte decreases as the concentration (\(c\)) increases. At infinite dilution (where \(c\) approaches zero), the molar conductivity approaches a maximum value (\(\lambda_0\)). 2. **Setting Concentration to Zero**: To find the relationship between \(\lambda\) and \(\lambda_0\), we can analyze the behavior of the equation as the concentration \(c\) approaches zero: \[ \lambda = \lambda_0 - A\sqrt{0} \] Simplifying this gives: \[ \lambda = \lambda_0 - 0 \] Therefore: \[ \lambda = \lambda_0 \] 3. **Interpreting the Result**: This result indicates that at infinite dilution (or when the concentration is zero), the molar conductivity equals the molar conductivity at infinite dilution, \(\lambda_0\). 4. **Identifying the Correct Option**: Based on our analysis, the equality that holds true is: \[ \lambda = \lambda_0 \quad \text{as} \quad c \to 0 \] 5. **Conclusion**: Thus, the correct answer to the question is that the equality holds when \(c\) approaches zero. ### Final Answer: The equality that holds is: \[ \lambda = \lambda_0 \quad \text{as} \quad c \to 0 \]

To solve the problem regarding the Debye-Huckel Onsager equation for strong electrolytes, we need to analyze the given equation: \[ \lambda = \lambda_0 - A\sqrt{c} \] where: - \(\lambda\) is the molar conductivity, ...
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