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Reduction potential of some ions are giv...

Reduction potential of some ions are given below. Arrange them in decreasing order of oxidising power.
`{:("Ion",ClO_(4)^(-),IO_(4)^(-),BrO_(4)^(-)),("Reduction",E^(Theta),E^(Theta)=1.65V,E^(Theta)=1.74V),("potential "E^(Theta)//V,,,):}`

A

`ClO_(4)^(-) gt IO_(4)^(-) gt BrO_(4)^(-)`

B

`IO_(4)^(-) gt BrO_(4)^(-) gt ClO_(4)^(-)`

C

`BrO_(4)^(-) gt IO_(4)^(-) gt ClO_(4)^(-)`

D

`BrO_(4)^(-) gt ClO_(4)^(-) gt IO_(4)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Higher the reduction potential higher is its tendency to get reduced. Hence, the order of oxidising power is:
`ClO_(4)^(-) gt IO_(4)^(-) gt BrO_(4)^(-)`.
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