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In a chemical reaction XtoY, it is found...

In a chemical reaction `XtoY`, it is found that the rate of reaction doubles when the concentration of X is incrased four times. The order of the reaction with respect to X is

A

1

B

0

C

2

D

`1//2`

Text Solution

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The correct Answer is:
To determine the order of the reaction with respect to X in the reaction \( X \to Y \), we can follow these steps: ### Step 1: Write the rate law expression The rate of a reaction can be expressed as: \[ \text{Rate} = k [X]^n \] where \( k \) is the rate constant, \( [X] \) is the concentration of reactant X, and \( n \) is the order of the reaction with respect to X. ### Step 2: Set up the initial conditions Let the initial concentration of X be \( [X] \). Therefore, the initial rate of the reaction can be expressed as: \[ R = k [X]^n \] ### Step 3: Analyze the change in concentration According to the problem, when the concentration of X is increased four times, the new concentration becomes \( 4[X] \). The new rate of reaction, denoted as \( R' \), can be expressed as: \[ R' = k (4[X])^n \] ### Step 4: Relate the rates We know from the problem that the rate doubles when the concentration is increased four times: \[ R' = 2R \] Substituting the expressions for \( R \) and \( R' \): \[ k (4[X])^n = 2(k [X]^n) \] ### Step 5: Simplify the equation We can simplify this equation: \[ k (4^n [X]^n) = 2k [X]^n \] Dividing both sides by \( k [X]^n \) (assuming \( k \) and \( [X] \) are not zero): \[ 4^n = 2 \] ### Step 6: Solve for \( n \) Now we need to solve for \( n \): \[ 4^n = 2 \implies (2^2)^n = 2 \implies 2^{2n} = 2^1 \] This implies: \[ 2n = 1 \implies n = \frac{1}{2} \] ### Conclusion The order of the reaction with respect to X is \( \frac{1}{2} \). ---

To determine the order of the reaction with respect to X in the reaction \( X \to Y \), we can follow these steps: ### Step 1: Write the rate law expression The rate of a reaction can be expressed as: \[ \text{Rate} = k [X]^n \] where \( k \) is the rate constant, \( [X] \) is the concentration of reactant X, and \( n \) is the order of the reaction with respect to X. ...
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