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Ambidentate ligands like NO(2)^(-) and ...

Ambidentate ligands like `NO_(2)^(-) and SCN^(-)` are :

A

unidentate

B

didentate

C

polydentate

D

has variable denticity

Text Solution

Verified by Experts

The correct Answer is:
A

Tetraamminequachloridocobalt (III) chloride is `[Co(NH_(3))_(4)(H_(2)O)Cl]Cl_(2)`.
Central atom - Cobalt(III)
Coordination sphere ligands -
Tetraammine - `4NH_(3)` groups neutral ligand
Aqua - `1H_(2)O` groups neutral ligand
Chlorido - 1 Cl group, negatively charged ligand, one negative charge
Counter ion Chloride ions 2.
Since Cobalt is 3 +, one valency is satisfied with Cl in coordination sphere and 2 by chlorine counter ions.
Hence, the formula of the coordination compound is `[CO(NH_(3))_(4)(H_(2)O)Cl]Cl_(2)`
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