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Assertion (A) [Cr(H(2)O(6))]Cl(2) and [F...

Assertion (A) `[Cr(H_(2)O_(6))]Cl_(2)` and `[Fe(H_(2)O)_(6)]Cl_(2)` are reducing in nature.
Reason (R) Unpaired electrons are present in their d-orbitals.

A

Both A and R are true but R is the correct expanation of A

B

Both A and R are true but R is NOT the correct expanation of A

C

A is true but R is false

D

A is false and R is true

Text Solution

Verified by Experts

The correct Answer is:
B

In the complexes, Co exists as `Co^(2+)` and Fe as `Fe^(2+)`. Both of the complexes become Stable by oxidation of metal ion to `Co^(3+)` and `Fe^(3+)`.
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