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In the following question, A statement o...

In the following question, A statement of Assertion (A) is followed by a statement of Reason (R). Mark the correct choice as.
Assertion (A): Extent of physisorption of a gas increases with decrease in temperature.
Reason (R): It is due to decrease in strength of van der Waals forces.

A

Both A and Rare true and R is the correct explanation of A

B

Both A and R are true but explanation of A

C

A is true but R is false

D

A is false and R is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the Assertion (A) and Reason (R), we will analyze both statements step by step. ### Step 1: Analyze the Assertion (A) **Assertion (A):** Extent of physisorption of a gas increases with decrease in temperature. - Physisorption is a type of adsorption that occurs due to weak van der Waals forces. - It is an exothermic process, meaning that heat is released when the gas molecules adhere to the surface. - According to Le Chatelier's principle, if the temperature decreases, the equilibrium shifts to favor the exothermic process, which in this case is physisorption. - Therefore, as the temperature decreases, the extent of physisorption indeed increases. **Conclusion for Assertion (A):** True. ### Step 2: Analyze the Reason (R) **Reason (R):** It is due to decrease in strength of van der Waals forces. - The statement suggests that the increase in physisorption with a decrease in temperature is because the strength of van der Waals forces decreases. - However, this is incorrect. The strength of van der Waals forces does not decrease with temperature; rather, the forces remain constant. - The reason for the increased extent of physisorption at lower temperatures is due to the exothermic nature of the process, not a decrease in the strength of the forces. **Conclusion for Reason (R):** False. ### Final Conclusion - Assertion (A) is true, while Reason (R) is false. Therefore, the correct choice is that the Assertion is true, but the Reason is false. ### Summary of the Answer - Assertion (A) is true. - Reason (R) is false. - The answer is option 3.

To solve the question regarding the Assertion (A) and Reason (R), we will analyze both statements step by step. ### Step 1: Analyze the Assertion (A) **Assertion (A):** Extent of physisorption of a gas increases with decrease in temperature. - Physisorption is a type of adsorption that occurs due to weak van der Waals forces. - It is an exothermic process, meaning that heat is released when the gas molecules adhere to the surface. - According to Le Chatelier's principle, if the temperature decreases, the equilibrium shifts to favor the exothermic process, which in this case is physisorption. ...
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