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Which one of the following is not applic...

Which one of the following is not applicable to the phenomenon of adsorption?

A

`Delta H gt 0`

B

`Delta G lt 0`

C

`Delta S lt 0`

D

`Delta H lt 0`

Text Solution

Verified by Experts

The correct Answer is:
A

Adsorption is an exothermic process, so the `Delta H` of adsorption is always negative.
`Delta H lt 0`
`Delta G=Delta H-T Delta S`
`Delta G` = Change in Gibbs free energy
`Delta H` = Change in enthalpy
T = Temperature in Kelvin
`Delta G` = Change in entropy
Since, adsorption is a spontaneous process, the thermodynamic requirement is at constant temperature and pressure, `Delta G` must be negative. So the enthalpy `Delta H` as well as entropy `Delta S` of the system is negative.
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