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A compound is prepared from gypsum upon ...

A compound is prepared from gypsum upon heating to a temperature of 373 K and it changes back to gypsum on adding water. Which is the incorrect statement about the compound?

A

The compound is used for setting fractured bones.

B

The compound is called plaster of Paris which is calcium sulphate dehydrate with a formula `CaSO_(4).2HO`.

C

If heated at higher temperature, the compound becomes dehydrated and is called dead burnt plaster.

D

Both (A) and (B).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the information given about the compound prepared from gypsum and determine which statement is incorrect. Here’s a step-by-step solution: ### Step 1: Identify Gypsum and Its Formula Gypsum is a mineral composed of calcium sulfate dihydrate. Its chemical formula is: \[ \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \] ### Step 2: Heating Gypsum When gypsum is heated to a temperature of 373 K (which is approximately 100 °C), it loses water and transforms into a different compound known as Plaster of Paris. The reaction can be represented as: \[ \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \xrightarrow{\text{heat}} \text{CaSO}_4 \cdot \frac{1}{2}\text{H}_2\text{O} + \text{1.5H}_2\text{O} \text{ (as steam)} \] ### Step 3: Identify the Compound Formed The compound formed after heating gypsum is called Plaster of Paris, which has the formula: \[ \text{CaSO}_4 \cdot \frac{1}{2}\text{H}_2\text{O} \] This is also referred to as calcium sulfate hemihydrate. ### Step 4: Rehydration of Plaster of Paris When water is added to Plaster of Paris, it rehydrates and converts back to gypsum: \[ \text{CaSO}_4 \cdot \frac{1}{2}\text{H}_2\text{O} + \text{1.5H}_2\text{O} \rightarrow \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \] ### Step 5: Analyze the Statements Now, we need to evaluate the statements provided in the question to find the incorrect one: 1. **The compound is used for setting fractured bones.** - This statement is correct. Plaster of Paris is indeed used for this purpose. 2. **The compound is called Plaster of Paris which is Calcium Sulfate Dihydrate with the formula CaSO4.2H2O.** - This statement is incorrect. Plaster of Paris is calcium sulfate hemihydrate, not dihydrate. Its correct formula is CaSO4.1/2H2O. 3. **If heated at higher temperature the compound becomes dehydrated and is called dead burnt plaster.** - This statement is correct. Heating Plaster of Paris at higher temperatures leads to the formation of anhydrous calcium sulfate, known as dead burnt plaster. 4. **Both A and B.** - This statement is also incorrect because statement A is correct. ### Conclusion The incorrect statement about the compound is: **The compound is called Plaster of Paris which is Calcium Sulfate Dihydrate with the formula CaSO4.2H2O.**

To solve the question, we need to analyze the information given about the compound prepared from gypsum and determine which statement is incorrect. Here’s a step-by-step solution: ### Step 1: Identify Gypsum and Its Formula Gypsum is a mineral composed of calcium sulfate dihydrate. Its chemical formula is: \[ \text{CaSO}_4 \cdot 2\text{H}_2\text{O} \] ### Step 2: Heating Gypsum When gypsum is heated to a temperature of 373 K (which is approximately 100 °C), it loses water and transforms into a different compound known as Plaster of Paris. The reaction can be represented as: ...
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