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The amount of energy required to break a...

The amount of energy required to break a bond is same as the amount of energy released when the same bond is formed. In gaseous state, the enrgy required for hololytic cleavage of a bond is called Bond Dissociation Energy(BDE) or Bond Strength. BDE is affected by s-character of the bond and the stability of the radicals formed. Shorter bonds typically stronger bonds. BDEs for some bonds are given below:
For the following reaction
`CH_4(g) + Cl_2(g) overset(light)rarr CH_3Cl(g) + HCl(g)`
the correct statement is

A

Initiation step is exothermic with `DeltaH^@ = -58kcal mol^(-1)`

B

Propagation step involving `dotCH_3` formation is exothermic with `DeltaH^@ = -2kcal mol^(-1)`

C

Propagation step involving `CH_3Cl` formation is endothermic with `DeltaH^@ = +27kcal mol^(-1)`

D

The reaction is exothermic with `DeltaH^@= -25kcalmol^(-1)`

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The amount of energy required to break a bond is same as the amount of energy released when the same bond is formed. In gaseous state, the enrgy required for hololytic cleavage of a bond is called Bond Dissociation Energy(BDE) or Bond Strength. BDE is affected by s-character of the bond and the stability of the radicals formed. Shorter bonds typically stronger bonds. BDEs for some bonds are given below: Correct match of the C-H bonds(shown in bold) in column J with their BDE in column K is

Bond energy

Knowledge Check

  • Energy required to break one bond in DNA is

    A
    `10^(-10) J`
    B
    `10^(-18) J`
    C
    `10^(-7)J`
    D
    `10^(-20) J`
  • Energy required to break one bond in DNA is approximately

    A
    `~1 eV`
    B
    `~0.1 eV`
    C
    `~0.01 eV`
    D
    `~2.1 eV`
  • The bond energy is the energy required to

    A
    dissociate oneemole of the substance
    B
    dissociate bond in 1 kg of the substance
    C
    break onemole of similar bonds
    D
    break bonds in one mole of substance
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