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A mixture of Cu^(2+) and Ni^(2+) can be ...

A mixture of `Cu^(2+) and Ni^(2+)` can be separated for identification by

A

passing `H_2 S` in acidic medium

B

passing `H_2 S` in alkaline medium

C

passing `H_2 S` in neutral medium

D

passing `H_2 S` in dry mixture

Text Solution

Verified by Experts

The correct Answer is:
A

By passing `H_2 S` gas in acidic medium in a mixture of `Cu^(2+)` and `Ni^(2+)`, only `Cu^(2+)` will be precipitated as CuS. `Ni^(2+)` will not be precipitated because its sulphide has much higher value of solubility product.
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