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Why is the activating effect of -NHCOCH3...

Why is the activating effect of `-NHCOCH_3` group in the above reaction less than the activating effect of amino group?

A

Due to mesomeric effect of benzene ring.

B

Due to inductive effect of alkyl group.

C

Due to resonance effect of acetanilide.

D

All of the above.

Text Solution

Verified by Experts

The correct Answer is:
C

The lone pair of electrons on nitrogen of acetanilide interacts with oxygen alom due to resonance as shown below :

Hence, the lone pair of electrons on nitrogen is less available for donation to benzene ring by resonance. Therefore, activating effect of `NHCOCH_3` group is less than that of amino group.
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