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One mole of O(2) gas is contained in a b...

One mole of `O_(2)` gas is contained in a box of volume `V=2m^(3)` at pressure `P_(0)` and temperature 300K The gas is now heated to 600 K and the molecules now get dissociated into oxygen atoms. The new pressure of the gas is

A

`P_(0)`

B

`2P_(0)`

C

`4P_(0)`

D

`8P_(0)`

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The correct Answer is:
To solve the problem, we will use the Ideal Gas Law and the relationship between pressure, volume, temperature, and the number of moles of gas. ### Step-by-Step Solution: 1. **Identify Initial Conditions:** - Initial moles of gas, \( N_1 = 1 \) mole (for \( O_2 \)) - Initial temperature, \( T_1 = 300 \, K \) - Initial pressure, \( P_1 = P_0 \) - Volume, \( V = 2 \, m^3 \) 2. **Identify Final Conditions:** - Final temperature, \( T_2 = 600 \, K \) - Since each \( O_2 \) molecule dissociates into 2 \( O \) atoms, the final moles of gas, \( N_2 = 2 \) moles (for \( O \)) - Volume remains the same, \( V = 2 \, m^3 \) 3. **Use the Ideal Gas Law:** - The relationship between pressure, volume, temperature, and number of moles can be expressed as: \[ \frac{P_1 \cdot N_1}{T_1} = \frac{P_2 \cdot N_2}{T_2} \] 4. **Substitute Known Values:** - Substitute \( P_1 = P_0 \), \( N_1 = 1 \), \( T_1 = 300 \), \( N_2 = 2 \), and \( T_2 = 600 \): \[ \frac{P_0 \cdot 1}{300} = \frac{P_2 \cdot 2}{600} \] 5. **Simplify the Equation:** - Rearranging gives: \[ P_0 \cdot 1 \cdot 600 = P_2 \cdot 2 \cdot 300 \] - This simplifies to: \[ 600 P_0 = 600 P_2 \] 6. **Solve for \( P_2 \):** - Dividing both sides by 300: \[ P_2 = \frac{600}{300} P_0 = 2 P_0 \] 7. **Final Calculation:** - Since we have \( N_2 = 2 \) moles, we need to account for the doubling of moles due to dissociation: \[ P_2 = 2 \cdot 2 P_0 = 4 P_0 \] ### Conclusion: The new pressure of the gas after heating and dissociation is \( P_2 = 4 P_0 \).
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