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Which of the following sets of ions repr...

Which of the following sets of ions represents the collection of isoelectronic species ?

A

`K^+,Ca^(2+),Sc^(3x),Cl^-`

B

`Na^+,Mg^(2+) ,Al^(3+),Cl^-`

C

`K^+,Cl^-,Mg^(2+),Sc^(3+)`

D

`Na^+,Ca^(2+),Sc^(3+),F^-`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which set of ions represents a collection of isoelectronic species, we need to find ions that have the same number of electrons. Let's analyze each option step by step. ### Step-by-Step Solution: **Step 1: Understand Isoelectronic Species** - Isoelectronic species are ions or atoms that have the same number of electrons. **Step 2: Analyze Each Option** **Option 1: K⁺, Ca²⁺, Sc³⁺, Cl⁻** - K (Potassium) has an atomic number of 19. When it loses one electron (K⁺), it has 18 electrons. - Ca (Calcium) has an atomic number of 20. When it loses two electrons (Ca²⁺), it also has 18 electrons. - Sc (Scandium) has an atomic number of 21. When it loses three electrons (Sc³⁺), it has 18 electrons. - Cl (Chlorine) has an atomic number of 17. When it gains one electron (Cl⁻), it has 18 electrons. **Conclusion for Option 1: All four ions have 18 electrons. Therefore, they are isoelectronic.** **Step 3: Check Other Options** **Option 2: Na⁺, Mg²⁺, Al³⁺, Cl⁻** - Na (Sodium) has an atomic number of 11. When it loses one electron (Na⁺), it has 10 electrons. - Mg (Magnesium) has an atomic number of 12. When it loses two electrons (Mg²⁺), it has 10 electrons. - Al (Aluminum) has an atomic number of 13. When it loses three electrons (Al³⁺), it has 10 electrons. - Cl (Chlorine) has an atomic number of 17. When it gains one electron (Cl⁻), it has 18 electrons. **Conclusion for Option 2: Na⁺, Mg²⁺, and Al³⁺ have 10 electrons, while Cl⁻ has 18 electrons. They are not isoelectronic.** **Option 3: K⁺, Cl⁻, Mg²⁺** - K⁺ has 18 electrons (as calculated before). - Cl⁻ has 18 electrons (as calculated before). - Mg²⁺ has 10 electrons (as calculated before). **Conclusion for Option 3: K⁺ and Cl⁻ have 18 electrons, but Mg²⁺ has 10 electrons. They are not isoelectronic.** **Option 4: Na⁺, Ca²⁺** - Na⁺ has 10 electrons (as calculated before). - Ca²⁺ has 18 electrons (as calculated before). **Conclusion for Option 4: Na⁺ has 10 electrons, while Ca²⁺ has 18 electrons. They are not isoelectronic.** ### Final Answer: The only set of ions that represents a collection of isoelectronic species is **Option 1: K⁺, Ca²⁺, Sc³⁺, Cl⁻**. ---
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