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B overset(CO,H2)underset("Oxo method")ra...

`B overset(CO,H_2)underset("Oxo method")rarr CH_3CH=CH_2 overset(O_2,PdCl_2,CuCl_2)underset(H_2O("Wacker method"))rarr A`
What is relation between A and B?

A

Analogues

B

Homologues

C

Both (1) and (2)

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the relationship between compounds A and B in the given reactions, we will analyze the reactions step by step. ### Step 1: Identify the starting compound B The starting compound B is represented as an alkene, specifically CH₃CH=CH₂ (propene). **Hint:** Look for the structure of the starting compound in the reaction. ### Step 2: Understand the Oxo method The Oxo method involves the hydroformylation of alkenes, where an alkene reacts with carbon monoxide (CO) and hydrogen (H₂) in the presence of a catalyst (like Cu) to form an aldehyde. In this case, propene (B) will react to form two possible aldehyde products. - The reaction can be represented as: - CH₃CH=CH₂ + CO + H₂ → CH₃CH₂CHO (butanal) or CH₃CHO (propanal) **Hint:** Remember that the Oxo method adds an aldehyde group to the alkene. ### Step 3: Understand the Wacker method The Wacker method involves the oxidation of alkenes using oxygen (O₂) in the presence of palladium chloride (PdCl₂) and copper chloride (CuCl₂) to form ketones. - For propene, the reaction can be represented as: - CH₃CH=CH₂ + O₂ → CH₃COCH₃ (acetone) **Hint:** The Wacker method typically converts alkenes to ketones. ### Step 4: Identify the products A and B From the above steps: - Product A is formed from the Wacker method and is a ketone (acetone). - Product B is formed from the Oxo method and can be an aldehyde (butanal or propanal). ### Step 5: Determine the relationship between A and B Both products A and B are derived from the same starting alkene (propene) but through different reactions. They are not homologous (not the same compound with a different number of carbon atoms), but they are analogous (they are both carbonyl compounds, one being a ketone and the other an aldehyde). **Conclusion:** A and B are analogous compounds derived from the same alkene through different reactions. **Final Answer:** A and B are analogous compounds.
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