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In the following reaction, MnO2 +4HCl ra...

In the following reaction, `MnO_2 +4HCl rarr MnCl_2 +2H_2O+CI_2` 2mole of `MnO_2` react with 4 moles of HCl to form 11.2L `Cl_2 ` at STP.
Thus, percent yield of `Cl_2`is

A

0.25

B

0.5

C

1

D

0.75

Text Solution

AI Generated Solution

The correct Answer is:
To find the percent yield of \( Cl_2 \) from the reaction \( MnO_2 + 4HCl \rightarrow MnCl_2 + 2H_2O + Cl_2 \), we will follow these steps: ### Step 1: Write down the balanced chemical equation The balanced equation for the reaction is: \[ MnO_2 + 4HCl \rightarrow MnCl_2 + 2H_2O + Cl_2 \] ### Step 2: Determine the moles of \( Cl_2 \) produced theoretically From the balanced equation, we see that 1 mole of \( MnO_2 \) produces 1 mole of \( Cl_2 \). Therefore, 2 moles of \( MnO_2 \) will produce 2 moles of \( Cl_2 \). ### Step 3: Calculate the volume of \( Cl_2 \) produced at STP At STP (Standard Temperature and Pressure), 1 mole of any gas occupies 22.4 liters. Thus, 2 moles of \( Cl_2 \) would occupy: \[ 2 \text{ moles} \times 22.4 \text{ L/mole} = 44.8 \text{ L} \] ### Step 4: Identify the actual yield of \( Cl_2 \) According to the problem, the actual yield of \( Cl_2 \) produced is 11.2 L. ### Step 5: Calculate the percent yield The percent yield can be calculated using the formula: \[ \text{Percent Yield} = \left( \frac{\text{Actual Yield}}{\text{Theoretical Yield}} \right) \times 100 \] Substituting the values: \[ \text{Percent Yield} = \left( \frac{11.2 \text{ L}}{44.8 \text{ L}} \right) \times 100 \] \[ \text{Percent Yield} = \left( \frac{11.2}{44.8} \right) \times 100 = 25\% \] ### Final Answer The percent yield of \( Cl_2 \) is **25%**. ---
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