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The solid-vapour equilibrium can be repr...

The solid-vapour equilibrium can be represented as
I `I_2(solid) rarr I_2(vapour)`
IIcamphor (solid)` iff `camphor (vapour)
III `NH_4Cl(solid) iff NH_4Cl(vapour)`
Point out the correct option(s).

A

I and II

B

Only II

C

II and III

D

All of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding solid-vapour equilibrium, we need to analyze each statement provided in the question. ### Step-by-Step Solution: 1. **Understanding Solid-Vapour Equilibrium**: - Solid-vapour equilibrium refers to the state where a solid and its vapour coexist at a certain temperature and pressure. This is typically represented using double arrows (⇌) to indicate that both the forward and reverse processes can occur. 2. **Analyzing Statement I**: - The first statement is: \[ I_2(solid) \rightarrow I_2(vapour) \] - This representation uses a single arrow, which indicates a one-way process. In equilibrium, we need to show that both the solid can turn into vapour and vapour can turn back into solid. Therefore, this representation is incorrect. 3. **Analyzing Statement II**: - The second statement is: \[ \text{camphor (solid)} \rightarrow \text{camphor (vapour)} \] - Similar to the first statement, this also uses a single arrow. For equilibrium, it should be represented as: \[ \text{camphor (solid)} \rightleftharpoons \text{camphor (vapour)} \] - Since it uses a single arrow, this representation is also incorrect. 4. **Analyzing Statement III**: - The third statement is: \[ NH_4Cl(solid) \rightarrow NH_4Cl(vapour) \] - Again, this uses a single arrow. The correct representation for equilibrium should be: \[ NH_4Cl(solid) \rightleftharpoons NH_4Cl(vapour) \] - Thus, this representation is also incorrect. 5. **Conclusion**: - After analyzing all three statements, we find that none of them correctly represent solid-vapour equilibrium. Therefore, the correct options are none. ### Final Answer: - None of the statements correctly represent solid-vapour equilibrium.
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