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In which of the following structures all...

In which of the following structures all the bonds are present at `90^@`?

A

Trigonal planar

B

tetrahedral

C

trigonal bipyramidal

D

octahedral

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which of the given structures all the bonds are present at `90°`, we need to analyze the bond angles in different molecular geometries. ### Step-by-Step Solution: 1. **Understanding Molecular Geometries**: - We need to identify the molecular geometries and their corresponding bond angles. The common geometries to consider are: - Trigonal planar - Tetrahedral - Trigonal bipyramidal - Octahedral 2. **Analyzing Trigonal Planar**: - In a trigonal planar geometry, such as in BCl3, the bond angles are `120°`. Therefore, this structure does not have all bonds at `90°`. 3. **Analyzing Tetrahedral**: - In a tetrahedral geometry, such as in CH4 (methane), the bond angles are `109.5°`. Thus, this structure also does not have all bonds at `90°`. 4. **Analyzing Trigonal Bipyramidal**: - In a trigonal bipyramidal geometry, such as in PCl5, there are two types of bond angles: `120°` in the equatorial plane and `90°` between the axial and equatorial positions. However, since not all bonds are at `90°`, this structure does not meet the requirement. 5. **Analyzing Octahedral Geometry**: - In an octahedral geometry, such as in SF6, there are six atoms arranged around a central atom. The bond angles between all adjacent bonds are `90°`. This means that all bonds in this structure are at `90°`. 6. **Conclusion**: - The only structure where all the bonds are present at `90°` is the octahedral structure. ### Final Answer: The structure in which all the bonds are present at `90°` is the **octahedral structure**.
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Knowledge Check

  • In which of the following molecules all the bonds are not equal:-

    A
    `CIF_(3)`
    B
    `BF_(3)`
    C
    ` AlF_(3) `
    D
    `NF_(3)`
  • In which of the following molecule/ion all the bonds are not equal ?

    A
    `XeF_(4)`
    B
    `BF_(4)^(-)`
    C
    `C_(2) H_(4)`
    D
    `SiF_(4)`
  • In which of the following molecule/ion all the bonds are not equal?

    A
    `XeF_(4)`
    B
    `BF_(4)^(-)`
    C
    `C_(2)H_(4)`
    D
    `SiF_(4)`
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