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This section contains Assertion and Reas...

This section contains Assertion and Reason type question each question has 4 choices (1)(2)(3)(4) out of which only one is correct
Assertion(A):`PCl_5` molecules has trigonal bipyramidal structure
Reason(R):The hybridisation of `PCl_5` is `sp_3d`

A

Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion

B

Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion

C

Assertion is correct but Reason is incorrect

D

Both Assertion and Reason are incorrect

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion and reason question regarding the structure and hybridization of \( PCl_5 \), we will analyze both the assertion and the reason step by step. ### Step 1: Analyze the Assertion **Assertion (A):** \( PCl_5 \) molecules have a trigonal bipyramidal structure. - **Explanation:** The molecular geometry of \( PCl_5 \) can be determined by considering the arrangement of its atoms. Phosphorus (P) is the central atom surrounded by five chlorine (Cl) atoms. In \( PCl_5 \), there are five bonding pairs of electrons and no lone pairs. This arrangement leads to a trigonal bipyramidal geometry, where three chlorine atoms occupy the equatorial positions and two chlorine atoms occupy the axial positions. ### Step 2: Analyze the Reason **Reason (R):** The hybridization of \( PCl_5 \) is \( sp^3d \). - **Explanation:** To determine the hybridization, we look at the number of sigma bonds and lone pairs around the central atom (phosphorus). In \( PCl_5 \), there are five sigma bonds formed between phosphorus and chlorine atoms. The hybridization that accommodates five regions of electron density (five sigma bonds) is \( sp^3d \). This hybridization corresponds to the trigonal bipyramidal geometry as well. ### Step 3: Conclusion - Both the assertion and the reason are correct. The reason provides a correct explanation for the assertion. ### Final Answer The correct choice is: **(1) Both assertion and reason are correct, and the reason is the correct explanation of the assertion.** ---
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