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Amongst elements of group 15, the proper...

Amongst elements of group 15, the property which decreases down the group is`//`are
I. electronegativity
II. stability of -3 oxidation state
III. acidic nature of oxides
Choose the correct option.

A

II and III

B

Only I

C

Only III

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the properties that decrease down the group among the elements of group 15, we will analyze each property one by one. ### Step 1: Identify the Elements of Group 15 Group 15 elements, also known as the nitrogen family, include: - Nitrogen (N) - Phosphorus (P) - Arsenic (As) - Antimony (Sb) - Bismuth (Bi) ### Step 2: Analyze Electronegativity Electronegativity is the ability of an atom to attract electrons in a chemical bond. - **Trend**: Electronegativity decreases down the group due to the increase in atomic radius (more electron shells) which reduces the effective nuclear charge experienced by the valence electrons. - **Conclusion**: Electronegativity decreases down the group. ### Step 3: Analyze Stability of -3 Oxidation State The -3 oxidation state is most stable for nitrogen and becomes less stable as we move down the group. - **Trend**: Nitrogen can easily accommodate three additional electrons, while heavier elements like bismuth can only exhibit positive oxidation states (e.g., +3). - **Conclusion**: Stability of the -3 oxidation state decreases down the group. ### Step 4: Analyze Acidic Nature of Oxides The acidic nature of oxides is influenced by the non-metallic character of the element. - **Trend**: As we move down the group, the non-metallic character decreases and the metallic character increases. Non-metal oxides are generally acidic, while metal oxides are basic. - **Conclusion**: The acidic nature of oxides decreases down the group. ### Step 5: Final Conclusion Based on the analysis: - I. Electronegativity decreases down the group. - II. Stability of -3 oxidation state decreases down the group. - III. Acidic nature of oxides decreases down the group. Thus, all the properties mentioned in the question decrease down the group. ### Correct Option The correct option is: **All of these (Option 4)**. ---
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