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Which of the following ions does not a p...

Which of the following ions does not a pseudohalide ion ?

A

`CN^-`

B

`SCN^-`

C

`ClF_3`

D

`ONC^-`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given ions is not a pseudohalide ion, we first need to understand what a pseudohalide is. Pseudohalides are anions that can behave similarly to halides (like fluoride, chloride, bromide, and iodide) in chemical reactions, particularly in forming acids with hydrogen ions (H⁺). ### Step-by-Step Solution: 1. **Understanding Pseudohalides**: - Pseudohalides are ions that can form compounds similar to those formed by halogens (Group 17 elements). They typically have a similar electronic configuration and can form stable anions. 2. **Identifying Halogens**: - Halogens include fluorine (F), chlorine (Cl), bromine (Br), and iodine (I). They have 7 valence electrons and tend to gain one electron to achieve a stable octet, forming anions like F⁻, Cl⁻, Br⁻, and I⁻. 3. **Evaluating Given Options**: - Let's consider the ions provided in the question (not specified in the prompt, but we will assume common pseudohalides and non-pseudohalides): - CN⁻ (cyanide ion) - SCN⁻ (thiocyanate ion) - ClF₃ (chlorine trifluoride) - N₃⁻ (azide ion) 4. **Analyzing Each Ion**: - **CN⁻**: This ion can bond with H⁺ to form HCN (hydrogen cyanide), behaving like a pseudohalide. - **SCN⁻**: This ion can also bond with H⁺ to form HSCN (thiocyanic acid), thus acting as a pseudohalide. - **ClF₃**: This is a neutral molecule and does not form an anion or bond with H⁺ to create an acid. Therefore, it does not behave like a pseudohalide. - **N₃⁻**: This ion can bond with H⁺ to form HN₃ (hydrazoic acid), functioning as a pseudohalide. 5. **Conclusion**: - Among the given options, ClF₃ does not act as a pseudohalide because it does not form an acid with H⁺. Therefore, the correct answer is ClF₃. ### Final Answer: **ClF₃ is not a pseudohalide ion.**
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