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The correct name of [Pt(NH3)4Cl2][PtCl4]...

The correct name of `[Pt(NH_3)_4Cl_2][PtCl_4]` is

A

tetrachloridoplantinum (II) dichloro dotertrammine platinate

B

dichlordotrammine platinum (IV) tetrachloroplatinate (II)

C

diamminedichloroplatinum (IV) tetrachlor ldo platinum (II)

D

tetrachlor ldo platinum (II) tetraammineplatinum (IV)

Text Solution

AI Generated Solution

The correct Answer is:
To name the compound \([Pt(NH_3)_4Cl_2][PtCl_4]\), we will follow the systematic naming conventions for coordination compounds. Here is a step-by-step breakdown of the naming process: ### Step 1: Identify the Cationic and Anionic Parts The compound consists of two parts: - The cationic part: \([Pt(NH_3)_4Cl_2]^+\) - The anionic part: \([PtCl_4]^{2-}\) ### Step 2: Name the Cationic Part 1. **Identify the ligands**: - The ligands present are ammonia (\(NH_3\)) and chloride (\(Cl^-\)). - Ammonia is a neutral ligand and is named as "amine". - Chloride is a negatively charged ligand and is named as "chlorido". 2. **Count the ligands**: - There are 4 ammonia ligands, which is indicated by the prefix "tetra-". - There are 2 chloride ligands, which is indicated by the prefix "di-". 3. **Arrange ligands in alphabetical order**: - Alphabetically, "amine" comes before "chlorido". 4. **Combine the names**: - The name of the cationic part is "tetraammine dichloridoplatinum". 5. **Determine the oxidation state of platinum**: - The total charge contributed by the ligands is \(0 + (-2) = -2\) (from 2 chlorido ligands). - Therefore, the oxidation state of platinum must be \(+2\) to balance the overall charge to \(+1\) for the cation. ### Step 3: Name the Anionic Part 1. **Identify the ligands**: - The anionic part contains 4 chloride ligands. 2. **Count the ligands**: - There are 4 chloride ligands, which is indicated by the prefix "tetra-". 3. **Combine the names**: - The name of the anionic part is "tetrachloridoplatinate". 4. **Determine the oxidation state of platinum**: - The total charge from the 4 chloride ligands is \(-4\), so the oxidation state of platinum here is \(+4\). ### Step 4: Combine the Names Now, we can combine the names of the cationic and anionic parts: - The full name of the compound is "tetraammine dichloridoplatinum(II) tetrachloridoplatinate(II)". ### Final Answer The correct name of the compound \([Pt(NH_3)_4Cl_2][PtCl_4]\) is: **Tetraammine dichloridoplatinum(II) tetrachloridoplatinate(II)**. ---
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