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sigma(C-C):4,sigma(C-H):6,pi(C=C):1,pi(C...

`sigma_(C-C):4,sigma_(C-H):6,pi_(C=C):1,pi_(C=C):2.` These numbers of`sigma` and `pi` bonds are present in which of the following molecule? Choose the correct option.

A

`CH-=C-CH=CH-CH_3`

B

`CH_2=C=CH-CH_3`

C

`CH_2=CH-CH=CH-CH_3`

D

None of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given information about the number of sigma (σ) and pi (π) bonds in a molecule. ### Step-by-Step Solution: 1. **Identify the Given Bonds**: - We have: - σ (C-C) = 4 - σ (C-H) = 6 - π (C=C) = 1 - π (C=C) = 2 2. **Understanding Sigma and Pi Bonds**: - A sigma bond (σ) is formed by the head-on overlap of atomic orbitals. Each single bond is a sigma bond. - A pi bond (π) is formed by the side-to-side overlap of p-orbitals and is present in double and triple bonds. A double bond consists of one sigma and one pi bond, while a triple bond consists of one sigma and two pi bonds. 3. **Count the Total Bonds**: - From the information given: - The total number of C-C bonds (σ) is 4. - The total number of C-H bonds (σ) is 6. - The total number of π bonds is 3 (1 from one double bond and 2 from another double bond). 4. **Constructing the Molecule**: - To satisfy 4 σ (C-C) bonds, we can have a combination of single and double bonds. - To satisfy 6 σ (C-H) bonds, we can have multiple carbon atoms, each bonded to hydrogen. - The total number of π bonds indicates that there are at least two double bonds. 5. **Possible Structure**: - A possible structure could be a chain of carbon atoms with some double bonds and sufficient hydrogen atoms to satisfy the σ (C-H) bonds. - For example, a molecule like 1,3-butadiene (C4H6) has: - 4 σ (C-C) bonds (3 single bonds, 1 double bond) - 6 σ (C-H) bonds (each carbon bonded to sufficient hydrogen) - 2 π bonds from the two double bonds. 6. **Conclusion**: - Based on the analysis, the molecule that fits the criteria of having 4 σ (C-C) bonds, 6 σ (C-H) bonds, and 3 π bonds is likely to be a compound with multiple double bonds and a sufficient number of hydrogen atoms. ### Answer: The correct option is the molecule that has 4 σ (C-C) bonds, 6 σ (C-H) bonds, and 3 π bonds, which corresponds to a structure like 1,3-butadiene or a similar compound.
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