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The final product of the following seque...

The final product of the following sequence of reaction is
`CH_2=CH_2 overset(Br_2)underset(CCl_4)rarrA overset(KCN)rarrB overset(H^+/H_2O) rarrC`

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final product of the given sequence of reactions, let's break down each step systematically. ### Step 1: Reaction of Ethylene with Bromine Starting with ethylene (CH₂=CH₂), we react it with bromine (Br₂) in carbon tetrachloride (CCl₄). This is an electrophilic addition reaction. **Reaction:** \[ \text{CH}_2=CH_2 + \text{Br}_2 \xrightarrow{\text{CCl}_4} \text{Br-CH}_2-CH_2\text{-Br} \] **Product A:** The product formed is 1,2-dibromoethane (Br-CH₂-CH₂-Br). ### Step 2: Reaction with Potassium Cyanide Next, we treat the dibromoethane (Product A) with potassium cyanide (KCN). This reaction involves nucleophilic substitution where the bromine atoms are replaced by cyanide ions (CN⁻). **Reaction:** \[ \text{Br-CH}_2-CH_2-\text{Br} + 2 \text{KCN} \rightarrow \text{CH}_2-C(=N) \text{C} \text{(CN)}_2 \] **Product B:** The final product of this step is 1,2-dicyanoethane (CH₂-C(CN)₂). ### Step 3: Hydrolysis with Acid and Water Finally, we hydrolyze the dicyano compound (Product B) using an acid (H⁺) and water (H₂O). This reaction converts the nitrile groups (CN) into carboxylic acid groups (COOH). **Reaction:** \[ \text{CH}_2-C(CN)_2 + 2 \text{H}_2O \xrightarrow{H^+} \text{CH}_2-C(COOH)_2 \] **Final Product C:** The final product is 1,2-ethanediol (HOOC-CH₂-COOH), which is a dicarboxylic acid. ### Summary of Products: - **Product A:** 1,2-dibromoethane (Br-CH₂-CH₂-Br) - **Product B:** 1,2-dicyanoethane (CH₂-C(CN)₂) - **Final Product C:** 1,2-ethanediol (HOOC-CH₂-COOH)
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