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beta-elimination is not possible in...

`beta-`elimination is not possible in

A

`CHCl_3`

B

`(CH_3)_3CBr`

C

`(CH_3)_2CHBr`

D

`(CH_3)_2CHCH_2Br`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the impossibility of beta-elimination in certain compounds, we need to understand the concept of beta-elimination and identify the presence of beta-hydrogens in the given options. ### Step-by-Step Solution: 1. **Understanding Beta-Elimination**: - Beta-elimination is a reaction where a molecule loses atoms or groups from the beta position (the carbon adjacent to the carbon bearing the leaving group) along with a leaving group. For this reaction to occur, the beta carbon must have at least one hydrogen atom (beta hydrogen) that can be removed. 2. **Analyzing the Options**: - We need to evaluate each option to check for the presence of beta hydrogens. 3. **Option 1: CHCl3 (Chloroform)**: - Structure: CHCl3 has one carbon (alpha carbon) attached to three chlorine atoms and one hydrogen atom. - There is no beta carbon present because there are no adjacent carbons. Therefore, there are no beta hydrogens. - Conclusion: Beta-elimination is **not possible** in CHCl3. 4. **Option 2: CH3-CHBr-CH3 (Bromoethane)**: - Structure: This compound has a carbon chain where the central carbon (alpha carbon) is attached to a bromine atom and two methyl groups (CH3). - The adjacent carbons (beta carbons) have hydrogen atoms. Thus, beta hydrogens are present. - Conclusion: Beta-elimination **is possible** in this compound. 5. **Option 3: CH3-CH2-CHBr-CH3 (Bromobutane)**: - Structure: This compound has a carbon chain where the central carbon (alpha carbon) is attached to a bromine atom and two ethyl groups. - The adjacent carbons (beta carbons) have hydrogen atoms. Thus, beta hydrogens are present. - Conclusion: Beta-elimination **is possible** in this compound. 6. **Option 4: CH3-CHBr-CH2-CH3 (Bromobutane)**: - Structure: Similar to the previous option, this compound has a carbon chain where the central carbon (alpha carbon) is attached to a bromine atom and two other carbons. - The adjacent carbons (beta carbons) have hydrogen atoms. Thus, beta hydrogens are present. - Conclusion: Beta-elimination **is possible** in this compound. 7. **Final Conclusion**: - Among the options analyzed, only **Option 1 (CHCl3)** does not have beta hydrogens, making beta-elimination impossible in this compound. ### Answer: Beta-elimination is not possible in **CHCl3**.
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