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In the reaction, RCN rarr RCH2NH2 Se...

In the reaction,
`RCN rarr RCH_2NH_2`
Select the correct statements (s) about the reaction.
I.It is oxidation reaction.
II. Reagents used in this reaction is `LiAlH_4, H_2/Ni,Na(Hg)/C_2H_5OH`.
Choose the correct option

A

Only I

B

Only II

C

I and II

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the reaction \( RCN \rightarrow RCH_2NH_2 \) and determine the correctness of the statements provided, we can follow these steps: ### Step 1: Identify the Type of Reaction - The reaction involves the conversion of a nitrile (\( RCN \)) to a primary amine (\( RCH_2NH_2 \)). - This transformation involves the addition of hydrogen to the carbon-nitrogen bond, which means that the nitrile is being reduced to an amine. ### Conclusion for Step 1: - Since the reaction involves a reduction process (gain of hydrogen), **Statement I** ("It is an oxidation reaction") is **incorrect**. ### Step 2: Identify the Reagents Used - The reagents mentioned are \( LiAlH_4 \), \( H_2/Ni \), and \( Na(Hg)/C_2H_5OH \). - \( LiAlH_4 \) (Lithium aluminum hydride) is a strong reducing agent that can reduce nitriles to primary amines. - \( H_2/Ni \) (hydrogen gas in the presence of nickel catalyst) is also a reducing agent that can facilitate the reduction of nitriles to amines. - \( Na(Hg)/C_2H_5OH \) (sodium amalgam in ethanol) can also act as a reducing agent for this transformation. ### Conclusion for Step 2: - All the mentioned reagents are indeed reducing agents that can convert nitriles to amines, making **Statement II** ("Reagents used in this reaction is \( LiAlH_4, H_2/Ni, Na(Hg)/C_2H_5OH \)") **correct**. ### Final Answer: - The correct option is that only **Statement II** is correct.
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