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Mutarotation does not occur in:...

Mutarotation does not occur in:

A

D-Glucose

B

Sucrose

C

L-Glucose

D

Both (a) and (b)

Text Solution

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The correct Answer is:
To determine which compound does not exhibit mutarotation, we first need to understand what mutarotation is. ### Step-by-Step Solution: 1. **Definition of Mutarotation**: - Mutarotation is the change in the optical rotation of a solution as it reaches equilibrium between two anomeric forms of a sugar. This typically occurs in sugars that can exist in both alpha (α) and beta (β) forms. 2. **Understanding Anomers**: - Anomers are a type of stereoisomer that differ in configuration at the anomeric carbon (the carbon that was the carbonyl carbon in the open-chain form). For example, glucose has two anomers: α-D-glucose and β-D-glucose. 3. **Identifying the Sugars**: - The question provides three options: D-glucose, L-glucose, and sucrose. - D-glucose and L-glucose are both monosaccharides that can exist in α and β forms, thus they can undergo mutarotation. - Sucrose, on the other hand, is a disaccharide composed of glucose and fructose. It does not have an anomeric carbon that can freely interconvert between forms. 4. **Conclusion**: - Since D-glucose and L-glucose can undergo mutarotation due to their anomeric forms, while sucrose cannot, the answer to the question is that mutarotation does not occur in sucrose. ### Final Answer: Mutarotation does not occur in **sucrose**. ---

To determine which compound does not exhibit mutarotation, we first need to understand what mutarotation is. ### Step-by-Step Solution: 1. **Definition of Mutarotation**: - Mutarotation is the change in the optical rotation of a solution as it reaches equilibrium between two anomeric forms of a sugar. This typically occurs in sugars that can exist in both alpha (α) and beta (β) forms. 2. **Understanding Anomers**: ...
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