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Among the following given compounds. Whi...

Among the following given compounds. Which of the following compounds on oxidation gives ethyl methyl ketone?

A

tert-butyl alcohol

B

1-butanol

C

2-butanol

D

3-propanol

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound on oxidation gives ethyl methyl ketone, we need to analyze the structures of the given compounds and their oxidation products. Ethyl methyl ketone (also known as 3-pentanone) has the structure CH3-CO-CH2-CH3. ### Step-by-Step Solution: 1. **Identify the Structure of Ethyl Methyl Ketone:** - Ethyl methyl ketone has the structure: \[ CH_3-CO-CH_2-CH_3 \] - This indicates that we are looking for a compound that, upon oxidation, will yield this structure. 2. **Examine the First Compound (Tertiary Butyl Alcohol):** - The structure of tertiary butyl alcohol is: \[ (CH_3)_3C-OH \] - Upon oxidation, tertiary alcohols do not oxidize because they lack hydrogen atoms on the carbon bearing the hydroxyl group. Therefore, this compound cannot yield ethyl methyl ketone. 3. **Examine the Second Compound (1-Butanol):** - The structure of 1-butanol is: \[ CH_3-CH_2-CH_2-CH_2-OH \] - Upon oxidation, 1-butanol would oxidize to butanal (an aldehyde), not to a ketone. Thus, this compound also cannot yield ethyl methyl ketone. 4. **Examine the Third Compound (2-Butanol):** - The structure of 2-butanol is: \[ CH_3-CH(OH)-CH_2-CH_3 \] - Upon oxidation, 2-butanol will oxidize to 2-butanone (a ketone), which has the structure: \[ CH_3-CO-CH_2-CH_3 \] - This matches the structure of ethyl methyl ketone. Therefore, this compound is a candidate. 5. **Examine the Fourth Compound (3-Propanol):** - The structure of 3-propanol is not valid as it does not exist. The valid alcohols are 1-propanol and 2-propanol. Thus, this option can be disregarded. 6. **Conclusion:** - The only compound that, upon oxidation, gives ethyl methyl ketone is **2-butanol**. Therefore, the correct answer is option number 3. ### Final Answer: **Option 3 (2-Butanol) is the correct answer.**

To determine which compound on oxidation gives ethyl methyl ketone, we need to analyze the structures of the given compounds and their oxidation products. Ethyl methyl ketone (also known as 3-pentanone) has the structure CH3-CO-CH2-CH3. ### Step-by-Step Solution: 1. **Identify the Structure of Ethyl Methyl Ketone:** - Ethyl methyl ketone has the structure: \[ CH_3-CO-CH_2-CH_3 ...
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