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Which of the following is isoelectronic ...

Which of the following is isoelectronic pair ?

A

`ICl_2 , ClO_2`

B

`BrO_2^- , BrF_2^+`

C

`ClO_2 , BrF`

D

`CN^(-) , O_3`

Text Solution

Verified by Experts

The correct Answer is:
B

Isoelectronic species are the species that possess the same number of total electrons. The number of electrons in each of the species is calculated as shown below:
`Icl_2 = 53 + (2 xx 17) = 87`
`ClO_2 = 17 + (2 xx 8) = 33`
`BrO_2^(-) = 35 + (2 xx 8) + 1 = 52`
`BrF_2^(+) = 35 + (2 xx 9) - 1 = 52`
`BrF = 35 + 9 = 44 `
`CN^(-) = 6 + 7 + 1 = 14`
`O_3 = 3 xx 8 = 24`
The ions `BrO_2^(-)` and `BrF_2^+` possess the same number of electrons. Therefore, the pair `BrO_2^(-)`, `BrF_2^+` is isoelectronic
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