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The increasing order of nucleophilicity ...

The increasing order of nucleophilicity is:

A

`I^(-) lt Cl^(-) lt Br^-`

B

`Br^(-) lt Cl^(-) lt I^-`

C

`Cl^(-) lt Br^(-) lt I^-`

D

`I^(-) lt Br^(-) lt Cl^(-)`

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The correct Answer is:
To determine the increasing order of nucleophilicity among the given halides (I^-, Br^-, Cl^-), we need to consider the size of the anions and their ability to donate electron pairs. ### Step-by-Step Solution: 1. **Understand Nucleophilicity**: Nucleophilicity refers to the ability of a species to donate an electron pair to an electrophile. Generally, larger anions are better nucleophiles because they can stabilize the negative charge more effectively. 2. **Identify the Anions**: The anions given in the question are I^-, Br^-, and Cl^-. 3. **Determine the Size of Anions**: The size of the halide ions increases as we move down the group in the periodic table: - Cl^- (Chloride) is the smallest. - Br^- (Bromide) is larger than Cl^-. - I^- (Iodide) is the largest. 4. **Relate Size to Nucleophilicity**: Since nucleophilicity increases with the size of the anion, we can establish the following relationship: - I^- > Br^- > Cl^- 5. **Write the Increasing Order of Nucleophilicity**: The increasing order of nucleophilicity among the given anions is: - Cl^- < Br^- < I^- ### Final Answer: The increasing order of nucleophilicity is: **Cl^- < Br^- < I^-** ---

To determine the increasing order of nucleophilicity among the given halides (I^-, Br^-, Cl^-), we need to consider the size of the anions and their ability to donate electron pairs. ### Step-by-Step Solution: 1. **Understand Nucleophilicity**: Nucleophilicity refers to the ability of a species to donate an electron pair to an electrophile. Generally, larger anions are better nucleophiles because they can stabilize the negative charge more effectively. 2. **Identify the Anions**: The anions given in the question are I^-, Br^-, and Cl^-. ...
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