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Electronic configuration of Zn,Cd and Hg...

Electronic configuration of Zn,Cd and Hg is

A

`(n-1)d^10ns^2`

B

`(n-1)d^9ns^2`

C

`(n-1)d^8ns^2`

D

`(n-1)^8ns^2np^1`

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The correct Answer is:
To find the electronic configurations of zinc (Zn), cadmium (Cd), and mercury (Hg), we need to understand their positions in the periodic table and how electrons fill the orbitals. ### Step-by-Step Solution: 1. **Identify the Elements**: - Zinc (Zn) has an atomic number of 30. - Cadmium (Cd) has an atomic number of 48. - Mercury (Hg) has an atomic number of 80. 2. **Determine the Electron Configuration**: - The general electronic configuration for transition metals in the d-block is given by the formula: \[ \text{(N-1)d}^{10} \text{Ns}^2 \] - Here, N represents the principal quantum number of the outermost shell. 3. **Electronic Configuration of Zinc (Zn)**: - Zinc is in the 4th period. - Therefore, its configuration is: \[ \text{Zn: } [\text{Ar}] 3d^{10} 4s^2 \] - This means that zinc has 10 electrons in the 3d subshell and 2 electrons in the 4s subshell. 4. **Electronic Configuration of Cadmium (Cd)**: - Cadmium is in the 5th period. - Its configuration is: \[ \text{Cd: } [\text{Kr}] 4d^{10} 5s^2 \] - This indicates that cadmium has 10 electrons in the 4d subshell and 2 electrons in the 5s subshell. 5. **Electronic Configuration of Mercury (Hg)**: - Mercury is in the 6th period. - Its configuration is: \[ \text{Hg: } [\text{Xe}] 4f^{14} 5d^{10} 6s^2 \] - This shows that mercury has 14 electrons in the 4f subshell, 10 electrons in the 5d subshell, and 2 electrons in the 6s subshell. ### Final Electronic Configurations: - **Zinc (Zn)**: \[ [\text{Ar}] 3d^{10} 4s^2 \] - **Cadmium (Cd)**: \[ [\text{Kr}] 4d^{10} 5s^2 \] - **Mercury (Hg)**: \[ [\text{Xe}] 4f^{14} 5d^{10} 6s^2 \]
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