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Although both CO2 and H2O are triatomic ...

Although both `CO_2` and `H_2O` are triatomic molecules, the shape of the `H_2O` molecule is bent while that of `CO_2` is linear. This is because

A

C is less electronegative than H

B

C is more electronegative than H

C

lone pairs are present on O atom of `H_2O` but not in O atom Of `CO_2`

D

lone pairs carrying O is the central atom in `H_2O` but not in `CO_2`

Text Solution

AI Generated Solution

The correct Answer is:
To understand why the shapes of \( H_2O \) and \( CO_2 \) differ despite both being triatomic molecules, we need to analyze their molecular structures and the role of lone pairs in determining molecular geometry. ### Step-by-Step Solution: 1. **Identify the Molecular Structures**: - **Water (\( H_2O \))**: The molecule consists of one oxygen atom bonded to two hydrogen atoms. Oxygen has two lone pairs of electrons. - **Carbon Dioxide (\( CO_2 \))**: The molecule consists of one carbon atom double bonded to two oxygen atoms. Carbon has no lone pairs. 2. **Determine the Electron Geometry**: - For \( H_2O \): - The central atom is oxygen, which has 2 bonded pairs (from the two \( H \) atoms) and 2 lone pairs. - The electron geometry is tetrahedral due to the four regions of electron density (2 bonds + 2 lone pairs). - For \( CO_2 \): - The central atom is carbon, which has 2 double bonds (one with each \( O \)) and no lone pairs. - The electron geometry is linear because there are only 2 regions of electron density. 3. **Apply VSEPR Theory**: - According to VSEPR (Valence Shell Electron Pair Repulsion) theory, lone pairs repel more strongly than bonded pairs. - In \( H_2O \), the two lone pairs push the hydrogen atoms closer together, resulting in a bent shape. - In \( CO_2 \), there are no lone pairs on the central atom (carbon), so the molecule maintains a linear shape. 4. **Conclusion**: - The difference in shape arises from the presence of lone pairs on the oxygen atom in \( H_2O \), which causes repulsion and results in a bent structure, while \( CO_2 \) is linear due to the absence of lone pairs on the carbon atom. ### Final Answer: The shape of \( H_2O \) is bent while that of \( CO_2 \) is linear because \( H_2O \) has two lone pairs on the central oxygen atom that cause repulsion, leading to a bent shape, whereas \( CO_2 \) has no lone pairs on the central carbon atom, resulting in a linear shape.
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