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Sodium acetate is electrolysed with wate...

Sodium acetate is electrolysed with water `(H_2O)`. The product formed at cathode is

A

`CH_4`

B

`CO_2`

C

`H_2`

D

NaOH

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product formed at the cathode during the electrolysis of sodium acetate (CH₃COONa) with water, we can follow these steps: ### Step 1: Understand the Electrolysis Process Electrolysis involves the decomposition of a compound into its elements or simpler compounds using electricity. In this case, we are electrolyzing sodium acetate in an aqueous solution. ### Step 2: Identify the Components Sodium acetate dissociates in water to give sodium ions (Na⁺) and acetate ions (CH₃COO⁻): \[ \text{CH}_3\text{COONa} \rightarrow \text{Na}^+ + \text{CH}_3\text{COO}^- \] ### Step 3: Determine the Reactions at the Electrodes During electrolysis, oxidation occurs at the anode and reduction occurs at the cathode. - **At the Anode:** The acetate ion (CH₃COO⁻) can undergo oxidation. The possible products include carbon dioxide (CO₂) and ethane (C₂H₆), among others. - **At the Cathode:** The reduction reaction typically involves the reduction of water or the cation present. In this case, the sodium ion (Na⁺) is not reduced because it is a strong reducing agent. Instead, water is reduced to form hydrogen gas (H₂). ### Step 4: Write the Cathode Reaction The reduction of water at the cathode can be represented as: \[ 2H_2O + 2e^- \rightarrow H_2 + 2OH^- \] ### Step 5: Conclusion The product formed at the cathode during the electrolysis of sodium acetate with water is hydrogen gas (H₂). ### Final Answer The product formed at the cathode is **H₂ (hydrogen gas)**. ---
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