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Cr2O7^(2-)//H^+ is an oxidising agent fo...

`Cr_2O_7^(2-)//H^+` is an oxidising agent for alcohol. Stage of completion is indicated by

A

green colour

B

blue colour

C

orange colour

D

yellow colour

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the oxidation of alcohol by the dichromate ion \((Cr_2O_7^{2-})\) in an acidic medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: We are given that \((Cr_2O_7^{2-})\) is an oxidizing agent for alcohol. Let's consider methanol \((CH_3OH)\) as our alcohol for this reaction. 2. **Understand the Role of \((Cr_2O_7^{2-})\)**: The dichromate ion \((Cr_2O_7^{2-})\) acts as a strong oxidizing agent in acidic medium. In this case, it will oxidize the alcohol (methanol) to a carboxylic acid (methanoic acid). 3. **Determine the Oxidation States**: In \((Cr_2O_7^{2-})\), chromium is in the +6 oxidation state. The oxidation state can be calculated as follows: \[ 2X + 7(-2) = -2 \quad \Rightarrow \quad 2X - 14 = -2 \quad \Rightarrow \quad 2X = 12 \quad \Rightarrow \quad X = +6 \] Thus, chromium is in the +6 oxidation state. 4. **Reaction Process**: When methanol is oxidized, it forms methanoic acid: \[ CH_3OH \rightarrow HCOOH \] During this reaction, the chromium in \((Cr_2O_7^{2-})\) is reduced from +6 to +3. 5. **Color Change Observation**: The initial color of \((Cr_2O_7^{2-})\) in solution is orange. After the reaction, as chromium is reduced to +3, the solution changes color: - Chromium in the +3 state is green. 6. **Conclusion**: Therefore, the stage of completion of the reaction can be indicated by the color change from orange to green. This signifies that the reaction has gone to completion, and \((Cr^{3+})\) is now present in the solution. ### Final Answer: The stage of completion is indicated by a **green color**. ---
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