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CH3Br can be prepared by...

`CH_3Br` can be prepared by

A

`CH_3COOAg+Br_2 overset Delta rarr`

B

`Ch_3COOH overset(P//Br_2) rarr overset (Sodallme.Delta) rarr`

C

Both (1) and (2)

D

None of the above

Text Solution

AI Generated Solution

The correct Answer is:
To prepare CH₃Br (methyl bromide), we can consider two main reactions that can yield this alkyl halide. Let's break down the steps for each reaction. ### Step-by-Step Solution: 1. **Identify the Compound**: - CH₃Br is an alkyl halide, specifically methyl bromide, where CH₃ is the methyl group and Br is the bromine atom. 2. **Consider the First Reaction**: - The first option is CH₃CoAg + Br₂. This is known as the Hans Dekker reaction. - In this reaction, CH₃CoAg (methylcopper) reacts with bromine (Br₂). - The reaction is a step-down reaction, meaning that the carbon count in the substrate decreases. 3. **Reaction Mechanism**: - The reaction proceeds as follows: \[ \text{CH}_3\text{CoAg} + \text{Br}_2 \rightarrow \text{CH}_3\text{Br} + \text{CO}_2 + \text{Ag} \] - Here, the methyl group (CH₃) is retained, and bromine is added, resulting in the formation of CH₃Br, while carbon dioxide (CO₂) and silver (Ag) are released. 4. **Consider the Second Reaction**: - The second option is CH₃CoH + PBr₂. This is known as the HVZ (Hunsdiecker-Van Duyne) reaction. - In this reaction, CH₃CoH (methylcobalt) reacts with phosphorus tribromide (PBr₂). 5. **Reaction Mechanism**: - The reaction proceeds as follows: \[ \text{CH}_3\text{CoH} + \text{PBr}_2 \rightarrow \text{CH}_3\text{Br} + \text{COOH} + \text{PBr}_3 \] - In this case, the methyl group (CH₃) is retained, and bromine is added, resulting in the formation of CH₃Br. 6. **Conclusion**: - Both reactions lead to the formation of CH₃Br. Therefore, both options are valid methods to prepare CH₃Br. ### Final Answer: CH₃Br can be prepared by both the Hans Dekker reaction (CH₃CoAg + Br₂) and the HVZ reaction (CH₃CoH + PBr₂).
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