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The most stable conformation of n-butane...

The most stable conformation of n-butane is

A

skew

B

eclipsed

C

staggered

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most stable conformation of n-butane, we will analyze the different conformations: staggered, eclipsed, and skew. ### Step-by-Step Solution: 1. **Understanding n-butane Structure**: - n-butane has the molecular formula C4H10. It consists of a straight chain of four carbon atoms (C1, C2, C3, C4) with hydrogen atoms attached. 2. **Identifying Conformations**: - The three main conformations of n-butane are: - **Staggered Conformation**: In this arrangement, the hydrogen atoms (or groups) on adjacent carbon atoms are positioned as far apart as possible. This minimizes steric hindrance and torsional strain. - **Eclipsed Conformation**: In this arrangement, the hydrogen atoms (or groups) on adjacent carbon atoms are aligned with each other. This maximizes steric hindrance and torsional strain. - **Skew Conformation**: This is an intermediate conformation between staggered and eclipsed, where the groups are not completely aligned but still have some overlap. 3. **Drawing the Structures**: - **Staggered**: Draw the n-butane chain with the CH3 groups on opposite sides, leading to maximum separation. - **Eclipsed**: Draw the n-butane chain with the CH3 groups directly aligned, leading to maximum overlap. - **Skew**: Draw the n-butane chain with CH3 groups at a 60-degree angle to each other. 4. **Analyzing Stability**: - **Staggered Conformation**: This is the most stable conformation due to minimal steric hindrance and torsional strain. - **Skew Conformation**: This is less stable than staggered but more stable than eclipsed. - **Eclipsed Conformation**: This is the least stable due to maximum steric hindrance and torsional strain. 5. **Conclusion**: - The most stable conformation of n-butane is the staggered conformation. ### Final Answer: The most stable conformation of n-butane is the **staggered conformation**.
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