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A compound that gives a positive iodofor...

A compound that gives a positive iodoform test is

A

pentan-1-ol

B

pentane-3-one

C

pentane-2-one

D

pentanal

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound gives a positive iodoform test, we need to identify the presence of a methyl ketone group (–C(=O)CH3) in the given options. The iodoform test is a chemical reaction that indicates the presence of this specific functional group. ### Step-by-Step Solution: 1. **Understand the Iodoform Test**: - The iodoform test is used to identify compounds that contain a methyl ketone group (–C(=O)CH3) or ethanol (ethyl alcohol) derivatives. The test involves the reaction of the compound with iodine (I2) in the presence of a base (NaOH), producing a yellow precipitate of iodoform (CHI3). 2. **Analyze the Given Options**: - We will examine each option to see if it contains a methyl ketone group. 3. **Option 1: Pentan-1-ol**: - Structure: CH3-CH2-CH2-CH2-OH - Analysis: This compound is a primary alcohol and does not have a ketone group. Therefore, it cannot give a positive iodoform test. 4. **Option 2: Pentan-2-ol**: - Structure: CH3-C(=O)-CH2-CH2-CH3 - Analysis: This compound has a methyl group adjacent to a carbonyl group (C=O). It is a secondary alcohol with a methyl ketone structure. Thus, it will give a positive iodoform test. 5. **Option 3: Pentanal**: - Structure: CH3-CH2-CH2-CHO - Analysis: This compound is an aldehyde and does not contain a methyl ketone group. Therefore, it will not give a positive iodoform test. 6. **Conclusion**: - The only compound that gives a positive iodoform test is **Pentan-2-ol**. ### Final Answer: **Pentan-2-ol** gives a positive iodoform test.
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