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Two mole of argon are mixed with one mol...

Two mole of argon are mixed with one mole of hydrogen, then `C_p/C_V` for the mixture is nearly

A

1,2

B

1,3

C

1,4

D

1,54

Text Solution

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The correct Answer is:
To find the ratio \( \frac{C_p}{C_V} \) (denoted as \( \gamma \)) for a mixture of gases, we can use the following steps: ### Step 1: Identify the gases and their properties - We have 2 moles of Argon (Ar) which is a monoatomic gas. - We have 1 mole of Hydrogen (H₂) which is a diatomic gas. ### Step 2: Determine the values of \( \gamma \) for each gas - For Argon (monoatomic gas), \( \gamma_1 = \frac{C_p}{C_V} = \frac{5}{3} \). - For Hydrogen (diatomic gas), \( \gamma_2 = \frac{C_p}{C_V} = 1.4 \). ### Step 3: Use the formula for the mixture The formula for the ratio \( \gamma \) of a mixture of two gases is given by: \[ \gamma_{mixture} = \frac{n_1 \gamma_1 + n_2 \gamma_2}{n_1 + n_2} \] Where: - \( n_1 \) = number of moles of Argon = 2 - \( n_2 \) = number of moles of Hydrogen = 1 - \( \gamma_1 \) = \( \frac{5}{3} \) - \( \gamma_2 \) = 1.4 ### Step 4: Substitute the values into the formula Now substituting the values into the formula: \[ \gamma_{mixture} = \frac{(2 \times \frac{5}{3}) + (1 \times 1.4)}{2 + 1} \] ### Step 5: Calculate the numerator Calculating the numerator: \[ 2 \times \frac{5}{3} = \frac{10}{3} \] \[ 1 \times 1.4 = 1.4 \] Now, convert 1.4 to a fraction: \[ 1.4 = \frac{14}{10} = \frac{7}{5} \] Finding a common denominator (15): \[ \frac{10}{3} = \frac{50}{15} \] \[ \frac{7}{5} = \frac{21}{15} \] Adding these: \[ \frac{50}{15} + \frac{21}{15} = \frac{71}{15} \] ### Step 6: Calculate the denominator The denominator is: \[ n_1 + n_2 = 2 + 1 = 3 \] ### Step 7: Final calculation of \( \gamma_{mixture} \) Now substitute back into the equation: \[ \gamma_{mixture} = \frac{\frac{71}{15}}{3} = \frac{71}{45} \approx 1.577 \] ### Step 8: Round to two decimal places Rounding gives us: \[ \gamma_{mixture} \approx 1.54 \] ### Conclusion Thus, the ratio \( \frac{C_p}{C_V} \) for the mixture is nearly \( 1.54 \). ---
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