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What will be the major product when 2-br...

What will be the major product when 2-bromopentane is treated with alc. KOH:

A

But-2-ene

B

Pent-2-ene

C

Pent-1-ene

D

2-methylbut-ene

Text Solution

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The correct Answer is:
To determine the major product when 2-bromopentane is treated with alcoholic KOH, we can follow these steps: ### Step 1: Identify the structure of 2-bromopentane 2-bromopentane has the following structure: - It consists of a five-carbon chain (pentane) with a bromine atom attached to the second carbon. - The structure can be represented as: ``` CH3-CH(Br)-CH2-CH2-CH3 ``` ### Step 2: Understand the reaction with alcoholic KOH Alcoholic KOH is a strong base and will promote elimination reactions (E2 mechanism) rather than substitution reactions. This means that it will remove a hydrogen atom and the bromine atom to form a double bond. ### Step 3: Determine possible elimination sites In 2-bromopentane, there are two possible sites from which the base can abstract a hydrogen atom: 1. From the carbon adjacent to the bromine (C1). 2. From the carbon on the other side of the bromine (C3). ### Step 4: Draw the potential products 1. If the hydrogen is removed from C1: - The product will be pent-1-ene (double bond between C1 and C2): ``` CH2=CH-CH2-CH2-CH3 (pent-1-ene) ``` 2. If the hydrogen is removed from C3: - The product will be pent-2-ene (double bond between C2 and C3): ``` CH3-CH=CH-CH2-CH3 (pent-2-ene) ``` ### Step 5: Analyze the stability of the products According to Zaitsev's rule, the more substituted alkene is generally the major product. In this case: - Pent-1-ene has a double bond between C1 and C2, making it less substituted. - Pent-2-ene has a double bond between C2 and C3, making it more substituted (two alkyl groups attached to the double bond). ### Step 6: Identify the major product Since pent-2-ene is more substituted and thus more stable than pent-1-ene, the major product of the reaction will be: - **Pent-2-ene**. ### Conclusion The major product when 2-bromopentane is treated with alcoholic KOH is **pent-2-ene**. ---

To determine the major product when 2-bromopentane is treated with alcoholic KOH, we can follow these steps: ### Step 1: Identify the structure of 2-bromopentane 2-bromopentane has the following structure: - It consists of a five-carbon chain (pentane) with a bromine atom attached to the second carbon. - The structure can be represented as: ``` ...
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