Home
Class 12
CHEMISTRY
The structure of XeOF2 is:...

The structure of `XeOF_2` is:

A

distorted octahedral

B

T-shaped

C

pyramidal

D

tetrahedral

Text Solution

AI Generated Solution

The correct Answer is:
To determine the structure of `XeOF2`, we can follow these steps: ### Step 1: Determine the Valence Electrons - **Xenon (Xe)** has 8 valence electrons. - **Oxygen (O)** has 6 valence electrons. - **Fluorine (F)** has 7 valence electrons, and since there are 2 fluorine atoms, we have \(2 \times 7 = 14\) valence electrons from fluorine. Total valence electrons = \(8 (Xe) + 6 (O) + 14 (F) = 28\) valence electrons. ### Step 2: Determine the Steric Number - The steric number is calculated by adding the number of bonded atoms and lone pairs on the central atom (Xe). - In `XeOF2`, there are 2 fluorine atoms and 1 oxygen atom bonded to xenon, which gives us 3 bonded atoms. - We will also consider the lone pairs on xenon. To find the number of lone pairs: - Each bond (2 F and 1 O) uses 2 electrons, so \(3 \text{ bonds} \times 2 = 6\) electrons are used. - Remaining electrons = \(28 - 6 = 22\) electrons. - Each lone pair uses 2 electrons, so \(22 \div 2 = 11\) lone pairs. However, we need to check how many lone pairs are actually on xenon. The correct calculation is: - For 3 bonds, we have \(3 \text{ bond pairs}\). - The total number of electron pairs (bonding + lone pairs) = \(28 / 2 = 14\). - Therefore, \(14 - 3 = 11\) lone pairs is incorrect. We need to adjust our understanding based on the geometry. ### Step 3: Hybridization - The steric number is 5 (3 bond pairs + 2 lone pairs). - The hybridization corresponding to a steric number of 5 is \(sp^3d\). ### Step 4: Determine the Geometry and Shape - The geometry of `XeOF2` with a steric number of 5 and 2 lone pairs is trigonal bipyramidal. - The presence of lone pairs will affect the shape. The lone pairs will occupy the equatorial positions to minimize repulsion. - This leads to a T-shaped molecular geometry. ### Conclusion The structure of `XeOF2` is T-shaped.

To determine the structure of `XeOF2`, we can follow these steps: ### Step 1: Determine the Valence Electrons - **Xenon (Xe)** has 8 valence electrons. - **Oxygen (O)** has 6 valence electrons. - **Fluorine (F)** has 7 valence electrons, and since there are 2 fluorine atoms, we have \(2 \times 7 = 14\) valence electrons from fluorine. Total valence electrons = \(8 (Xe) + 6 (O) + 14 (F) = 28\) valence electrons. ...
Promotional Banner

Topper's Solved these Questions

  • SAMPLE PAPER 04

    EDUCART PUBLICATION|Exercise SECTION B|24 Videos
  • SAMPLE PAPER 04

    EDUCART PUBLICATION|Exercise SECTION C|6 Videos
  • SAMPLE PAPER 02

    EDUCART PUBLICATION|Exercise SECTION - C|6 Videos
  • SAMPLE PAPER 05

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos