Home
Class 12
CHEMISTRY
What is the structure of BrF5 :...

What is the structure of `BrF_5` :

A

Pentagonal bipyramidal

B

Octahedral

C

Square pyramidal

D

Bent T-shape

Text Solution

AI Generated Solution

The correct Answer is:
To determine the structure of \( \text{BrF}_5 \), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in Group 17 (halogens) and has 7 valence electrons. Each fluorine (F) atom has 7 valence electrons, and since there are 5 fluorine atoms, the total contribution from fluorine is \( 5 \times 7 = 35 \) electrons. **Total valence electrons:** \[ \text{Valence electrons from Br} + \text{Valence electrons from 5 F} = 7 + 35 = 42 \text{ electrons} \] ### Step 2: Calculate the Electron Pairs To find the number of electron pairs, we divide the total number of valence electrons by 2: \[ \text{Total electron pairs} = \frac{42}{2} = 21 \text{ pairs} \] ### Step 3: Determine the Hybridization Since bromine is the central atom and it forms 5 bonds with fluorine, we need to consider the hybridization. The number of bonding pairs is 5 and the number of lone pairs can be calculated as follows: \[ \text{Lone pairs} = \text{Total pairs} - \text{Bonding pairs} = 21 - 5 = 1 \text{ lone pair} \] The hybridization can be determined by the formula: - 5 bonding pairs + 1 lone pair = 6 electron pairs → \( \text{SP}^3\text{D}^2 \) ### Step 4: Determine the Geometry The geometry corresponding to \( \text{SP}^3\text{D}^2 \) hybridization is octahedral. However, since there is 1 lone pair, the molecular shape will be different from the geometry. ### Step 5: Identify the Molecular Shape With 5 bonding pairs and 1 lone pair, the molecular shape is derived from the octahedral arrangement but with one position occupied by a lone pair. This results in a square pyramidal shape. ### Final Structure Thus, the structure of \( \text{BrF}_5 \) is square pyramidal. ### Summary - **Valence Electrons**: 42 - **Electron Pairs**: 21 - **Hybridization**: \( \text{SP}^3\text{D}^2 \) - **Geometry**: Octahedral - **Molecular Shape**: Square Pyramidal

To determine the structure of \( \text{BrF}_5 \), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in Group 17 (halogens) and has 7 valence electrons. Each fluorine (F) atom has 7 valence electrons, and since there are 5 fluorine atoms, the total contribution from fluorine is \( 5 \times 7 = 35 \) electrons. **Total valence electrons:** \[ \text{Valence electrons from Br} + \text{Valence electrons from 5 F} = 7 + 35 = 42 \text{ electrons} ...
Promotional Banner

Topper's Solved these Questions

  • SAMPLE PAPER 04

    EDUCART PUBLICATION|Exercise SECTION C|6 Videos
  • SAMPLE PAPER 04

    EDUCART PUBLICATION|Exercise SECTION C|6 Videos
  • SAMPLE PAPER 02

    EDUCART PUBLICATION|Exercise SECTION - C|6 Videos
  • SAMPLE PAPER 05

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
EDUCART PUBLICATION-SAMPLE PAPER 04-SECTION B
  1. 18 g of sucrose is dissolved in 162 g of water Calcualte the mass per...

    Text Solution

    |

  2. CH3 Br underset("Dry ether")overset(Mg)to CH2MgBr overset(D2O)to B

    Text Solution

    |

  3. What is the structure of BrF5 :

    Text Solution

    |

  4. Which is not a reducing sugar?

    Text Solution

    |

  5. Which among the flowing compound(s) is/ are primary alcohol?

    Text Solution

    |

  6. In which compound oxygen does not show - 2 oxidation state:

    Text Solution

    |

  7. Structure of a mixed oxide is cubic closed - packed (ccp) .The cubic u...

    Text Solution

    |

  8. Among the given compounds which of the following is vinylic halides:

    Text Solution

    |

  9. Which of the following pairs of ions are isoelectronic and isostructur...

    Text Solution

    |

  10. Which of the following will have lowest vapour pressure?

    Text Solution

    |

  11. Which of the following reaction is not the evidence for presence aldeh...

    Text Solution

    |

  12. What is the IUPAC name of the compound:

    Text Solution

    |

  13. The value of a, b and c values in orthorhombic crystal are 4.2 Å, 8.6 ...

    Text Solution

    |

  14. The property of halogens which is not correctly matched is

    Text Solution

    |

  15. Which of the following reactions would give the best yield of t-butyl ...

    Text Solution

    |

  16. What will the major product of the following : C2H5ONa + CH3-underse...

    Text Solution

    |

  17. Which of the following statement is correct about dinitrogen?

    Text Solution

    |

  18. Identify X in the following reaction:

    Text Solution

    |

  19. Calculate the number of isomeric halopropanes produced, when propane g...

    Text Solution

    |

  20. Assertion (A): Nitrogen has diamagnetic in nature. Reason (R): Nit...

    Text Solution

    |