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What is the structure of BrF5 :...

What is the structure of `BrF_5` :

A

Pentagonal bipyramidal

B

Octahedral

C

Square pyramidal

D

Bent T-shape

Text Solution

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The correct Answer is:
To determine the structure of \( \text{BrF}_5 \), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in Group 17 (halogens) and has 7 valence electrons. Each fluorine (F) atom has 7 valence electrons, and since there are 5 fluorine atoms, the total contribution from fluorine is \( 5 \times 7 = 35 \) electrons. **Total valence electrons:** \[ \text{Valence electrons from Br} + \text{Valence electrons from 5 F} = 7 + 35 = 42 \text{ electrons} \] ### Step 2: Calculate the Electron Pairs To find the number of electron pairs, we divide the total number of valence electrons by 2: \[ \text{Total electron pairs} = \frac{42}{2} = 21 \text{ pairs} \] ### Step 3: Determine the Hybridization Since bromine is the central atom and it forms 5 bonds with fluorine, we need to consider the hybridization. The number of bonding pairs is 5 and the number of lone pairs can be calculated as follows: \[ \text{Lone pairs} = \text{Total pairs} - \text{Bonding pairs} = 21 - 5 = 1 \text{ lone pair} \] The hybridization can be determined by the formula: - 5 bonding pairs + 1 lone pair = 6 electron pairs → \( \text{SP}^3\text{D}^2 \) ### Step 4: Determine the Geometry The geometry corresponding to \( \text{SP}^3\text{D}^2 \) hybridization is octahedral. However, since there is 1 lone pair, the molecular shape will be different from the geometry. ### Step 5: Identify the Molecular Shape With 5 bonding pairs and 1 lone pair, the molecular shape is derived from the octahedral arrangement but with one position occupied by a lone pair. This results in a square pyramidal shape. ### Final Structure Thus, the structure of \( \text{BrF}_5 \) is square pyramidal. ### Summary - **Valence Electrons**: 42 - **Electron Pairs**: 21 - **Hybridization**: \( \text{SP}^3\text{D}^2 \) - **Geometry**: Octahedral - **Molecular Shape**: Square Pyramidal

To determine the structure of \( \text{BrF}_5 \), we can follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in Group 17 (halogens) and has 7 valence electrons. Each fluorine (F) atom has 7 valence electrons, and since there are 5 fluorine atoms, the total contribution from fluorine is \( 5 \times 7 = 35 \) electrons. **Total valence electrons:** \[ \text{Valence electrons from Br} + \text{Valence electrons from 5 F} = 7 + 35 = 42 \text{ electrons} ...
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