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Racemisation occurs in:...

Racemisation occurs in:

A

`S_(N)2`

B

`S_(N)1`

C

Neither `S_(N)2 "nor" S_(N)1"`.

D

`S_(N)2` reaction as well as ` S_(N)1` reaction

Text Solution

AI Generated Solution

The correct Answer is:
To determine where racemization occurs, we need to analyze the two types of nucleophilic substitution reactions: SN1 and SN2. ### Step-by-Step Solution: 1. **Understanding Racemization**: - Racemization refers to the process where a chiral compound is converted into a mixture of its enantiomers (equal amounts of R and S forms). This typically occurs when a reaction allows for the formation of a planar intermediate, which can be attacked from either side. 2. **Analyzing SN1 Mechanism**: - In an SN1 reaction, the mechanism involves two steps: - **Step 1**: The leaving group (e.g., Br) departs, forming a carbocation intermediate. This carbocation is planar and can be attacked by a nucleophile from either side. - **Step 2**: The nucleophile attacks the carbocation, leading to the formation of both R and S products, resulting in racemization. - Therefore, SN1 reactions can lead to racemization due to the formation of a planar carbocation. 3. **Analyzing SN2 Mechanism**: - In an SN2 reaction, the mechanism is a single concerted step: - The nucleophile attacks the substrate from the opposite side of the leaving group, leading to a direct displacement without forming a stable intermediate. - Since there is no planar intermediate and the attack occurs from one side only, racemization does not occur in SN2 reactions. 4. **Conclusion**: - Based on the analysis, racemization occurs in SN1 reactions due to the formation of a planar carbocation intermediate that allows for attack from both sides. In contrast, SN2 reactions do not allow for racemization because they proceed through a single transition state without forming a stable intermediate. ### Final Answer: Racemization occurs in **SN1 reactions**.

To determine where racemization occurs, we need to analyze the two types of nucleophilic substitution reactions: SN1 and SN2. ### Step-by-Step Solution: 1. **Understanding Racemization**: - Racemization refers to the process where a chiral compound is converted into a mixture of its enantiomers (equal amounts of R and S forms). This typically occurs when a reaction allows for the formation of a planar intermediate, which can be attacked from either side. 2. **Analyzing SN1 Mechanism**: ...
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