Home
Class 12
CHEMISTRY
Assertion (A): The reducing nature of hy...

Assertion (A): The reducing nature of hydrides of group 16 varies in the order:
`H_2O lt H_2S lt H_2Se lt H_2Te `
Reason (R): The bond dissociation enthalpy of hydrides of group 16 decreases in the order: `H_2O gt H_2S gt H_2Se gt H_2Te. `

A

Both A and Rare true and R is the correct explanation of A

B

Both A and Rare true but Ris not the correct explanation of A

C

A is true but R is false

D

A is false but R is true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step 1: Understanding the Assertion (A) The assertion states that the reducing nature of hydrides of group 16 varies in the order: \[ H_2O < H_2S < H_2Se < H_2Te \] **Explanation:** - Reducing agents are substances that can donate electrons or reduce other substances while being oxidized themselves. - In group 16, as we move down the group from oxygen to tellurium, the ability of the hydrides to act as reducing agents increases. This is because the bond strength of the H-X bond (where X is the group 16 element) decreases down the group, making it easier for the hydrogen to be released. ### Step 2: Understanding the Reason (R) The reason states that the bond dissociation enthalpy of hydrides of group 16 decreases in the order: \[ H_2O > H_2S > H_2Se > H_2Te \] **Explanation:** - Bond dissociation enthalpy is the energy required to break a bond. A higher bond dissociation enthalpy means the bond is stronger and harder to break. - As we move down group 16, the size of the atoms increases, leading to longer and weaker bonds between hydrogen and the group 16 element. Thus, the bond dissociation enthalpy decreases. ### Step 3: Connecting Assertion and Reason - The assertion is correct because the reducing nature increases down the group. - The reason is also correct because it accurately describes the trend in bond dissociation enthalpy. - Since the reason explains why the assertion is true, we conclude that both the assertion and reason are correct, and the reason is a correct explanation of the assertion. ### Conclusion Both the assertion and reason are correct, and the reason provided correctly explains the assertion. ### Final Answer Both Assertion (A) and Reason (R) are correct, and R is the correct explanation of A. ---

To solve the question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step 1: Understanding the Assertion (A) The assertion states that the reducing nature of hydrides of group 16 varies in the order: \[ H_2O < H_2S < H_2Se < H_2Te \] **Explanation:** - Reducing agents are substances that can donate electrons or reduce other substances while being oxidized themselves. ...
Promotional Banner

Topper's Solved these Questions

  • SAMPLE PAPER 05

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
  • SAMPLE PAPER 05

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
  • SAMPLE PAPER 04

    EDUCART PUBLICATION|Exercise SECTION C|6 Videos
  • SAMPLE PAPER 06

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
EDUCART PUBLICATION-SAMPLE PAPER 05-SECTION-B
  1. Which of the following is correct about H-bonding in nucleotide?

    Text Solution

    |

  2. The alcohol which does not react with Lucas reagent is:

    Text Solution

    |

  3. The boiling points of hydrides of group 16 are in the order

    Text Solution

    |

  4. A binary solid(A^(+) B^(-)) has a zinc blende stracture with B ions co...

    Text Solution

    |

  5. Which among the following forms a linear polymeric structure due to hy...

    Text Solution

    |

  6. The unit of ebullioscopic constant is

    Text Solution

    |

  7. In the given reaction : A, B, C and D respectively are:

    Text Solution

    |

  8. Which of the following is most reactive towards S(N)1 reaction?

    Text Solution

    |

  9. What will be the ratio of the total volume of bcc to simple cubic stru...

    Text Solution

    |

  10. Nitrogen is used to fill electric bulb because:

    Text Solution

    |

  11. The reagent that is used to convert phenol into benzene is:

    Text Solution

    |

  12. IUPAC name of the compund CH3-underset(CH3)underset(|)"CH"-OCH3is

    Text Solution

    |

  13. The correct order of Delta(i) H(1) values is:

    Text Solution

    |

  14. What happens when 1-Propanol in the presence of HBF4 reacts with diazo...

    Text Solution

    |

  15. Halogenation, sulphonation, Friedel-Craft's reaction of haloarenes is ...

    Text Solution

    |

  16. Assertion (A): The reducing nature of hydrides of group 16 varies in t...

    Text Solution

    |

  17. Assertion (A) Hydrolysis of (-)-2-bromooctane proceeds with inversion ...

    Text Solution

    |

  18. Assertion (A): Soft drinks are seated under high pressure to increase ...

    Text Solution

    |

  19. Assertion (A): Nitric oxide on heating becomes yellowish brown in colo...

    Text Solution

    |

  20. Assertion : Azeotropic mixtures are formed only by non - ideal solutio...

    Text Solution

    |