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Frenkel defect is not shown by:...

Frenkel defect is not shown by:

A

AgBr

B

ZnS

C

KBr

D

AgCl

Text Solution

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The correct Answer is:
To determine which compound does not exhibit a Frenkel defect, we need to understand what a Frenkel defect is and the conditions under which it occurs. ### Step-by-Step Solution: 1. **Definition of Frenkel Defect**: - A Frenkel defect occurs in a crystal lattice when a cation (or anion) is displaced from its normal position to an interstitial site, creating a vacancy at its original position. This defect typically occurs in ionic solids. 2. **Conditions for Frenkel Defect**: - For a Frenkel defect to occur, the cation must be relatively small compared to the anion. This is because a smaller cation can fit into the interstitial spaces between the larger anions without causing significant distortion to the lattice. 3. **Analyzing the Options**: - We need to analyze the given options to identify which compound does not fit the criteria for exhibiting a Frenkel defect. - The common compounds to consider include alkali metal halides and other ionic compounds. 4. **Identifying the Incorrect Option**: - Among the options, if we have KBr (Potassium Bromide), it is important to note that potassium (K⁺) is a relatively large cation compared to other cations like Ag⁺ (Silver) or Zn²⁺ (Zinc). - Since K⁺ is larger, it cannot fit into the interstitial sites of the lattice structure, thus KBr will not exhibit a Frenkel defect. 5. **Conclusion**: - Therefore, the compound that does not show a Frenkel defect is **KBr**. ### Final Answer: **KBr (Potassium Bromide) does not show Frenkel defect.** ---

To determine which compound does not exhibit a Frenkel defect, we need to understand what a Frenkel defect is and the conditions under which it occurs. ### Step-by-Step Solution: 1. **Definition of Frenkel Defect**: - A Frenkel defect occurs in a crystal lattice when a cation (or anion) is displaced from its normal position to an interstitial site, creating a vacancy at its original position. This defect typically occurs in ionic solids. 2. **Conditions for Frenkel Defect**: ...
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