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A metal crystallizes into two cubic phas...

A metal crystallizes into two cubic phases, face-centred cubic and body-centred cubic, which have unit cell lengths `3.5` and `3.0 A`, respectively. Calculate the ration of densities of fcc and bcc.

A

2.335

B

1.259

C

1.555

D

2.232

Text Solution

Verified by Experts

The correct Answer is:
B

Density `(rho) =(Z_("eff") xx M_(W))/(a^3 xx N_A)`
For fcc , `Z_("eff") = 4 `
`rho`fcc `=( 4xx M_w)/((3.5 xx 10^(-8))^3xx N_A)`
for bcc, `Z_("fcc") = 2 `
`rho`fcc = `(2xx M_w)/((3.5xx10^(-8))^3 xx N_A)`
`(rho "f1")/(rho f"cc") = (4 xx (3)^3)/(3.5)^3 xx 2) = 1.26`
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