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Optically active alkyl halides under goi...

Optically active alkyl halides under going `S_N 1` mechanism leads to:

A

retention of configuration

B

racemisation

C

inversion of configuration

D

both (a) and (c)

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The correct Answer is:
To solve the question about optically active alkyl halides undergoing an SN1 mechanism, we can break it down into several steps: ### Step 1: Understand the SN1 Mechanism The SN1 mechanism involves two main steps: 1. Formation of a carbocation after the leaving group departs. 2. Nucleophilic attack on the carbocation. ### Step 2: Identify the Starting Material We start with an optically active alkyl halide. This means the carbon attached to the halide (e.g., Cl) is a chiral center, having four different groups attached to it. ### Step 3: Formation of the Carbocation When the alkyl halide undergoes the SN1 reaction, the leaving group (Cl) departs, forming a carbocation. This carbocation is planar and can be attacked by a nucleophile from either side. ### Step 4: Nucleophilic Attack The nucleophile can attack the carbocation from two different orientations: - From above the plane of the carbocation. - From below the plane of the carbocation. ### Step 5: Resulting Products The two different orientations of attack will lead to two different products: 1. One product will have the nucleophile (e.g., OH) on the wedge (indicating it is above the plane). 2. The other product will have the nucleophile on the dash (indicating it is below the plane). ### Step 6: Analysis of the Products Since the original compound was chiral, and the nucleophile can attack from both sides, we end up with a racemic mixture of two enantiomers (one R and one S configuration). ### Step 7: Conclusion The overall result of the reaction leads to a racemic mixture, which is a 1:1 mixture of the two enantiomers. This process is called racemization. ### Final Answer The answer to the question is that optically active alkyl halides undergoing SN1 mechanism leads to **racemization**. ---

To solve the question about optically active alkyl halides undergoing an SN1 mechanism, we can break it down into several steps: ### Step 1: Understand the SN1 Mechanism The SN1 mechanism involves two main steps: 1. Formation of a carbocation after the leaving group departs. 2. Nucleophilic attack on the carbocation. ### Step 2: Identify the Starting Material ...
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EDUCART PUBLICATION-SAMPLE PAPER 07-SECTION-B
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  2. Optically active alkyl halides under going SN 1 mechanism leads to:

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  3. I2 is only slightly soluble in

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  4. In the given reaction: A, B, C and D respectively are:

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  5. Which of the following is an amorphous solid?

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  6. Which of the following oxides of nitrogen is the anhydride of nitrous ...

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  7. For a crystal having face centered cubic lattice, atom A occupies the ...

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  8. Identify A, B, C and D in the following reaction,

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  9. When excess chlorine is used in electrophilic substitution of toluene,...

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  10. Osmotic pressure present in the fluid inside the blood cell is equival...

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  11. Which of the following reaction is not the evidence for presence of al...

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  12. Lithium having a body centered cubic. Its density is 0.53 g cm^(-3) an...

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  13. Calculate the number of monochloro derivatives that formed when neo-pe...

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  14. The incorrect statement about Kolbe's reaction is?

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  15. The pka values of various compounds are mentioned below: Which i...

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  16. The correct order of DeltaH1 values is:

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  17. Among the following given compounds. Which of the following compounds ...

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  18. Which reagent will you use for the following reaction? CH3 CH2 CH...

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  19. Assertion (A): Noble gases have large positive values of electron gain...

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  20. Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc....

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