Home
Class 12
CHEMISTRY
Which of the following reaction is not t...

Which of the following reaction is not the evidence for presence of aldehyde:

A

Reaction glucose with hycloroxylamine

B

Reaction of glucose with `Br_2` water

C

Reaction of glucose HCN

D

Reaction of glucose with acetyle chloride

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reaction is not evidence for the presence of an aldehyde, we need to analyze the reactions involving glucose and identify the one that does not indicate the presence of the aldehyde functional group (–CHO). ### Step-by-Step Solution: 1. **Understanding the Structure of Glucose**: - Glucose is a six-carbon sugar with an aldehyde group. The structure can be represented as: ``` CHO-CHOH-CHOH-CHOH-CHOH-CH2OH ``` - The aldehyde group is at one end of the molecule. 2. **Identifying the Reactions**: - We have several reactions to consider: - Reaction with acetyl chloride - Reaction with hydroxylamine - Reaction with bromine water - Reaction with hydrogen cyanide (HCN) 3. **Analyzing Each Reaction**: - **Reaction with Acetyl Chloride**: - This reaction forms acetyl derivatives of glucose. It primarily reacts with the alcoholic groups present in glucose, rather than the aldehyde group. Thus, it does not provide direct evidence for the presence of the aldehyde group. - **Reaction with Hydroxylamine**: - Hydroxylamine reacts with aldehydes to form oximes. This reaction is a clear indication of the presence of the aldehyde group. - **Reaction with Bromine Water**: - Bromine water reacts with aldehydes to produce carboxylic acids. This reaction also confirms the presence of the aldehyde group. - **Reaction with Hydrogen Cyanide (HCN)**: - HCN reacts with aldehydes to form cyanohydrins, which is another indication of the presence of the aldehyde group. 4. **Conclusion**: - Among the reactions analyzed, the reaction with acetyl chloride does not provide evidence for the presence of the aldehyde group, as it primarily indicates the presence of alcoholic groups instead. ### Final Answer: The reaction that is not evidence for the presence of an aldehyde is the **reaction with acetyl chloride**. ---

To determine which reaction is not evidence for the presence of an aldehyde, we need to analyze the reactions involving glucose and identify the one that does not indicate the presence of the aldehyde functional group (–CHO). ### Step-by-Step Solution: 1. **Understanding the Structure of Glucose**: - Glucose is a six-carbon sugar with an aldehyde group. The structure can be represented as: ``` CHO-CHOH-CHOH-CHOH-CHOH-CH2OH ...
Promotional Banner

Topper's Solved these Questions

  • SAMPLE PAPER 07

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
  • SAMPLE PAPER 07

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
  • SAMPLE PAPER 06

    EDUCART PUBLICATION|Exercise SECTION-C|6 Videos
  • SAMPLE PAPER 10

    EDUCART PUBLICATION|Exercise SECTION - C|5 Videos
EDUCART PUBLICATION-SAMPLE PAPER 07-SECTION-B
  1. Which of the following is an amorphous solid?

    Text Solution

    |

  2. Which of the following oxides of nitrogen is the anhydride of nitrous ...

    Text Solution

    |

  3. For a crystal having face centered cubic lattice, atom A occupies the ...

    Text Solution

    |

  4. Identify A, B, C and D in the following reaction,

    Text Solution

    |

  5. When excess chlorine is used in electrophilic substitution of toluene,...

    Text Solution

    |

  6. Osmotic pressure present in the fluid inside the blood cell is equival...

    Text Solution

    |

  7. Which of the following reaction is not the evidence for presence of al...

    Text Solution

    |

  8. Lithium having a body centered cubic. Its density is 0.53 g cm^(-3) an...

    Text Solution

    |

  9. Calculate the number of monochloro derivatives that formed when neo-pe...

    Text Solution

    |

  10. The incorrect statement about Kolbe's reaction is?

    Text Solution

    |

  11. The pka values of various compounds are mentioned below: Which i...

    Text Solution

    |

  12. The correct order of DeltaH1 values is:

    Text Solution

    |

  13. Among the following given compounds. Which of the following compounds ...

    Text Solution

    |

  14. Which reagent will you use for the following reaction? CH3 CH2 CH...

    Text Solution

    |

  15. Assertion (A): Noble gases have large positive values of electron gain...

    Text Solution

    |

  16. Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc....

    Text Solution

    |

  17. Assertion (A): When scuba divers come towards surface, their capillari...

    Text Solution

    |

  18. Assertion (A): Chlorine water has both oxidising as well as bleaching ...

    Text Solution

    |

  19. Assertion : Acetone and aniline shows negative deviations. Reason : ...

    Text Solution

    |

  20. Assertion : Acetone and aniline shows negative deviations. Reason : ...

    Text Solution

    |