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initial rate method#!#temperature depend...

initial rate method#!#temperature dependence of rate

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The rate nitration of tuluene in nitromethane with excess of HNO_3 is constant and the reaction is zero order with respect to toluene. If the rate is temperature dependent, which of the following can be expected as a rate determining step?

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The temperature dependence of the rate of a chemical reaction can be explained by Arrhenius equaiton which is

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Intitial rate method: Use the following initial rate data determine the form of the rate law expressoin for the reaction 3X+2Yrarr2U+V Strategy: The rate law is of the form Rate = k[X]^(a)[Y]^(b) No two experiments have the same in initial [Y], thus, use the alternative method discussed earlier to evalaute a and b.