Home
Class 12
CHEMISTRY
CsBr crystallizes in a body-centred cubi...

`CsBr` crystallizes in a body-centred cubic unit lattice with an edge length of `4.287 Å`. Calculate the angles at which the second-order reflection maxima may be expected for `(2, 0, 0)`, `(1, 1, 0)`, planes when `X`-rays of `gamma = 0.50 Å` are used.

Text Solution

Verified by Experts

For `bc c` lattice, `d_(200) = a//2`
So, for second-orderreflection, `2gamma = 2 xx (a)/(2) sin theta_(1)`
or `sin theta_(1) = (2gamma)/(a)`
i.e., `sin theta_(1) = (2 xx 0.50)/(4.287)` and `theta_(1) = 13^(@)29'`
`d_(110) = (a)/(sqrt2)`
So, `2 gamma = 2 xx (a)/(sqrt2) sin theta_(2) = (sqrt2gamma)/(a)`.
`sin theta_(2) = (sqrt2 xx 0.50)/(4.284) implies theta_(2) = 9^(@)30'`
`d_(111) = (a)/(2sqrt3)`, so `2gamma = 2 xx (a)/(2sqrt3) sin theta_(3) implies sin theta_(3) = (2sqrt3gamma)/(a)`
i.e., `sin theta_(3) = (2 xx sqrt3 xx 0.50)/(4.287)` and `theta_(3) = 23^(@)49'`
Promotional Banner

Similar Questions

Explore conceptually related problems

Sodium metal crystallizes in a body centred cubic lattice with a unit cell edge of 4.29Å . The radius of sodium atom is approximately :

Chromium metal crystallizes with a body-centred cubic lattice. The length of the unit cell edge is found to be 287 pm. Calculate the atomic radius. What woulds be the density of chromium in g cm^(-3) ?

The X-ray of wavelength 1.5A^@ are incident on a crystal having an interatomic distance of 1.6A^@ . Find out the angles at which the first and second order reflection take place.

Potassium chloride crystallize with a body-centred cubic lattice. Calculate the distance between the 200, 110, and 222 Planes. The length of the side of the unit cell is 5.34 Å .

Lithium metal has a body centred cubic lattice structure with edge length of unit cell 353 pm . Calculate the density of the lithium metal. [Given : Atomic mass of Li = 7 g mol^(-1) , N_A = 6.022 xx 10^(23) atom mol^(-1) )

The direction ratios of a normal to the plane thro' (1,0,0), (0, 1, 0), which makes an angle of with pi/4 the plane x + y = 3 are :

Answer any five of the following questions. Lithium metal has a body centred cubic lattice structure with edge length of edge unit cell 352 pm. Calculate the density of lithium metal. [Given: Atomic mass of Li = 7 "gmol"^(-1) , N_(A) = 6.022 xx 10^(23) atoms mol ""^(-1) ].

A metal crystallizes into two cubic phases, face-centred cubic and body-centred cubic, which have unit cell lengths 3.5 and 3.0 A , respectively. Calculate the ratio of densities of fcc and bcc.

Using calculus, find the order relation between x and tan^(-1) x when x in (-oo,0].

The number of unit cells in the Ca atom lies on the surface of a cubic crystal that is 1.0 cm in length is