Home
Class 12
CHEMISTRY
Consider the cell : Cd(s)|Cd^(2+)(1.0M...

Consider the cell `:`
`Cd(s)|Cd^(2+)(1.0M)||Cu^(2+)(1.0M)|Cu(s)`
If we wish to make a cell with a more positive voltage using the same substances, we should

A

Increase both `[Cd^(2+)]` and `[Cu^(2+)]` to `2.0M`

B

Decrease the `[Cd^(2+]` to `1.0m`

C

Increase the `[Cu^(2+)]` to `2.0M`

D

Decrease both the `[Cd^(2+)]` and `[Cu^(2+)]` to `0.01M`

Text Solution

Verified by Experts

The correct Answer is:
b,c

`Cd(s)underset((1.0M))(+Cu^(2+))+rarr underset((1.0M))(C d^(2+)+)Cu(s)`
`E_(cell)=E^(c-)._(cell)-(0.059)/(2)log .([Cd^(2+)])/([Cu^(2+)])`
`E_(cell)` increases when conditions as in `(b)` and `(c)` made.
Promotional Banner

Similar Questions

Explore conceptually related problems

Consider the cell at 25^(@)C Tl"|"Tl^(+)(0.001M)"||"Cu^(2+)(0.10)M)"|"Cu for which e.m.f. is 0.84 V. The e.m.f. of this cell could be increased by

For the cell Zn(s)|Zn^(2+) (2M)||Cu^(2+) (0.5 M)|Cu(s) (a) Write equation for each half reaction. (b) Calculate the cell potential at 25^@C

For the cell reaction Zn(s) +Cu^(2+)(0.1M) rarr zn^(2+)(0.01M) + Cu(s) , If E^(@) is the strandard e.m.f. of the cell, then

For the cell reaction Fe(s)|Fe^(2+)(0.1M)"||"H^(+)(1M)|H_(3)"(1 atm)" , Pt E^(@)=0.44V . The cell e.m.f. is :

The electrode potential for the Danicell given below is 1.1V. Zn(s)|Zn^(2+)(aq)||Cu^(2+)(aq)|Cu(s) Write overall cell reaction and calculate the standard Gibb's energy for the reaction. [F=96487c//mol] .

The e.m.f. of the cell : Cu(s)"|"Cu^(2+)(1M)"||"Ag^(+)(1M)"|"Ag is 0.46 V. The standard reduction reduction potential of Ag^(+)//Ag is 0.80 V. The standard reduction potential of Cu^(2+)//Cu is

For the electrochemical cell : Zn "|"Zn^(2+)(1M)"||"H^(+)(1M)"|"H_(2)("atm") , Pt the e.m.f. of the cell has been found to be 0.76. The standard reduction potential of zinc is :

Standard EMF of the cell: Cu||Cu^(2+) (1m)||Ag^(+) (1m)|Ag is 0.46 at 25^@C . Find the value of standard free energy charge for the reaction that occurs in the cell.

The cell Zn | Zn ^(2+) (1M)||Cu ^(2+)(1M)|Cu (E ^(@) _(cell) = 1. 10V) was allowed to be completely discharged at 298 K. The relative concentration of Zn ^(2+) to Cu ^(2+) (([Zn ^(2+)])/([Cu^(2+)])) is :